A microcapsule-based reusable self-reporting system using a donor-acceptor Stenhouse adduct

Soonyoung Choi, Gyeong Eun Kim, Hyoungeun Bae, Su Jeong Choi, Ji Eun Jeong, Jin Chul Kim, Hanah Na, Hyocheol Jung, Yu Jin Jung, Sang Ho Lee, Young Il Park

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Self-reporting systems automatically indicate damaged or corroded surfaces via color changes or fluorescence. In this study, a novel reusable self-reporting system is developed by exploiting the reversibility of a donor-acceptor Stenhouse adduct (DASA). The synthesized DASA precursor exhibits a color change when damaged upon reaction with diethylamine, and returns to its colorless form upon irradiation with visible light. Microcapsules are synthesized with a core comprising styrene and the DASA precursor, along with a shell formed of urea and formaldehyde. The optimal particle size and shell thickness of the microcapsules are 225 μm and 0.17 μm, respectively. The DASA precursor-containing microcapsules are embedded in a PEG gel matrix with secondary amine groups. This coating system, initially colorless, exhibits a color change, becoming pink after being damaged by scratching due to the reaction between the DASA precursor released from ruptured microcapsules with the secondary amine groups of the PEG gel, thus demonstrating self-reporting characteristics. Furthermore, the colored surface is restored to its initial colorless state by irradiation with visible light for 1.5 hours, demonstrating the reusability of the self-reporting system.

Original languageEnglish
Pages (from-to)10653-10661
Number of pages9
JournalRSC Advances
Volume14
Issue number15
DOIs
StatePublished - 2 Apr 2024

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