A one-pot chemical route to prepare poly 4, 4′-diaminodiphenyl sulfone-zirconium dioxide/cerium dioxide hybrid nanocomposites for improved capacitance properties

Anandhavelu Sanmugam; Anandha Raj Jeyaraman; Sethuraman Venkatesan; Manisankar Paramasivam; Hyun Seok Kim; Dhanasekaran Vikraman

doi:10.1016/j.matlet.2019.04.048

A one-pot chemical route to prepare poly 4, 4′-diaminodiphenyl sulfone-zirconium dioxide/cerium dioxide hybrid nanocomposites for improved capacitance properties

Anandhavelu Sanmugam
, Anandha Raj Jeyaraman
, Sethuraman Venkatesan
, Manisankar Paramasivam
, Hyun Seok Kim
, Dhanasekaran Vikraman

Department of Electronics & Electrical Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Innovative hybrid composites of poly 4, 4′-diaminodiphenyl sulfone (PDDS)-zirconium dioxide (ZrO ₂ )/cerium dioxide (CeO ₂ ) were prepared using a chemical polymerization process. The functional groups were analyzed using Fourier transform infrared spectroscopy profiles that revealed polymer establishment through N[sbnd]H group stretching and in-plane bending vibrations about ∼3454 and ∼1623 cm ⁻¹ , respectively. Scanning electron microscopy and transmission electron microscopy images were used to explore the morphology of nano-sized grains in the hybrid composites. The improved electrochemical capacitance behavior was confirmed by cyclic voltammetry curves. Charge-discharge curves were used to determine capacitance values of 229 and 288 F·g ⁻¹ for PDDS-ZrO ₂ (15 wt%) and PDDS-CeO ₂ (15 wt%) nanocomposites, respectively.

Original language	English
Pages (from-to)	5-8
Number of pages	4
Journal	Materials Letters
Volume	249
DOIs	https://doi.org/10.1016/j.matlet.2019.04.048
State	Published - 15 Aug 2019

Keywords

Capacitance
FTIR
Nanocomposites
TEM

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10.1016/j.matlet.2019.04.048

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@article{739cbf67e22146e0969af4e0f24f52a1,

title = "A one-pot chemical route to prepare poly 4, 4′-diaminodiphenyl sulfone-zirconium dioxide/cerium dioxide hybrid nanocomposites for improved capacitance properties",

abstract = " Innovative hybrid composites of poly 4, 4′-diaminodiphenyl sulfone (PDDS)-zirconium dioxide (ZrO 2 )/cerium dioxide (CeO 2 ) were prepared using a chemical polymerization process. The functional groups were analyzed using Fourier transform infrared spectroscopy profiles that revealed polymer establishment through N[sbnd]H group stretching and in-plane bending vibrations about ∼3454 and ∼1623 cm −1 , respectively. Scanning electron microscopy and transmission electron microscopy images were used to explore the morphology of nano-sized grains in the hybrid composites. The improved electrochemical capacitance behavior was confirmed by cyclic voltammetry curves. Charge-discharge curves were used to determine capacitance values of 229 and 288 F·g −1 for PDDS-ZrO 2 (15 wt\%) and PDDS-CeO 2 (15 wt\%) nanocomposites, respectively.",

keywords = "Capacitance, FTIR, Nanocomposites, TEM",

author = "Anandhavelu Sanmugam and Jeyaraman, \{Anandha Raj\} and Sethuraman Venkatesan and Manisankar Paramasivam and Kim, \{Hyun Seok\} and Dhanasekaran Vikraman",

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year = "2019",

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doi = "10.1016/j.matlet.2019.04.048",

language = "English",

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journal = "Materials Letters",

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TY - JOUR

T1 - A one-pot chemical route to prepare poly 4, 4′-diaminodiphenyl sulfone-zirconium dioxide/cerium dioxide hybrid nanocomposites for improved capacitance properties

AU - Sanmugam, Anandhavelu

AU - Jeyaraman, Anandha Raj

AU - Venkatesan, Sethuraman

AU - Paramasivam, Manisankar

AU - Kim, Hyun Seok

AU - Vikraman, Dhanasekaran

PY - 2019/8/15

Y1 - 2019/8/15

N2 - Innovative hybrid composites of poly 4, 4′-diaminodiphenyl sulfone (PDDS)-zirconium dioxide (ZrO 2 )/cerium dioxide (CeO 2 ) were prepared using a chemical polymerization process. The functional groups were analyzed using Fourier transform infrared spectroscopy profiles that revealed polymer establishment through N[sbnd]H group stretching and in-plane bending vibrations about ∼3454 and ∼1623 cm −1 , respectively. Scanning electron microscopy and transmission electron microscopy images were used to explore the morphology of nano-sized grains in the hybrid composites. The improved electrochemical capacitance behavior was confirmed by cyclic voltammetry curves. Charge-discharge curves were used to determine capacitance values of 229 and 288 F·g −1 for PDDS-ZrO 2 (15 wt%) and PDDS-CeO 2 (15 wt%) nanocomposites, respectively.

AB - Innovative hybrid composites of poly 4, 4′-diaminodiphenyl sulfone (PDDS)-zirconium dioxide (ZrO 2 )/cerium dioxide (CeO 2 ) were prepared using a chemical polymerization process. The functional groups were analyzed using Fourier transform infrared spectroscopy profiles that revealed polymer establishment through N[sbnd]H group stretching and in-plane bending vibrations about ∼3454 and ∼1623 cm −1 , respectively. Scanning electron microscopy and transmission electron microscopy images were used to explore the morphology of nano-sized grains in the hybrid composites. The improved electrochemical capacitance behavior was confirmed by cyclic voltammetry curves. Charge-discharge curves were used to determine capacitance values of 229 and 288 F·g −1 for PDDS-ZrO 2 (15 wt%) and PDDS-CeO 2 (15 wt%) nanocomposites, respectively.

KW - Capacitance

KW - FTIR

KW - Nanocomposites

KW - TEM

UR - https://www.scopus.com/pages/publications/85064156782

U2 - 10.1016/j.matlet.2019.04.048

DO - 10.1016/j.matlet.2019.04.048

M3 - Article

AN - SCOPUS:85064156782

SN - 0167-577X

VL - 249

SP - 5

EP - 8

JO - Materials Letters

JF - Materials Letters

ER -

A one-pot chemical route to prepare poly 4, 4′-diaminodiphenyl sulfone-zirconium dioxide/cerium dioxide hybrid nanocomposites for improved capacitance properties

Abstract

Keywords

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