Abstract
A model for predicting the effects of stimuli-induced contraction of the polypyrrole ends of two-segment gold-polypyrrole nanorods on their assembly into curved superstructures is presented. The model and experimental data presented here show that small changes (ca. 3%) in the diameter of the polypyrrole segment of each rod will induce dramatic changes (up to 20%) in the radii of the resulting superstructures, providing a convenient means for actuating their opening and closing. We show experimentally that this actuation can be affected via humidity, temperature, and light.
| Original language | English |
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| Pages (from-to) | 4441-4445 |
| Number of pages | 5 |
| Journal | Nano Letters |
| Volume | 8 |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 2008 |