An asymmetric synthesis of (+)-isonitramine by 'triple allylic strain-controlled' intramolecular SN2' alkylation

Deukjoon Kim; Won Jun Choi; Ji Yong Hong; Yeong Park; Yang Bae Kim

doi:10.1016/0040-4039(96)00023-8

An asymmetric synthesis of (+)-isonitramine by 'triple allylic strain-controlled' intramolecular S_N2' alkylation

Deukjoon Kim, Won Jun Choi, Ji Yong Hong, Yeong Park, Yang Bae Kim

Department of Pharmacy

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The spirocyclic alkaloid (+)-isonitramine (1) has been synthesized in a stereoselective manner utilizing a novel 'triple allylic strain-controlled' intramolecular lactam enolate S_N2' alkylation.

Original language	English
Pages (from-to)	1433-1434
Number of pages	2
Journal	Tetrahedron Letters
Volume	37
Issue number	9
DOIs	https://doi.org/10.1016/0040-4039(96)00023-8
State	Published - 26 Feb 1996

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title = "An asymmetric synthesis of (+)-isonitramine by 'triple allylic strain-controlled' intramolecular SN2' alkylation",

abstract = "The spirocyclic alkaloid (+)-isonitramine (1) has been synthesized in a stereoselective manner utilizing a novel 'triple allylic strain-controlled' intramolecular lactam enolate SN2' alkylation.",

author = "Deukjoon Kim and Choi, {Won Jun} and Hong, {Ji Yong} and Yeong Park and Kim, {Yang Bae}",

year = "1996",

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T1 - An asymmetric synthesis of (+)-isonitramine by 'triple allylic strain-controlled' intramolecular SN2' alkylation

AU - Kim, Deukjoon

AU - Choi, Won Jun

AU - Hong, Ji Yong

AU - Park, Yeong

AU - Kim, Yang Bae

PY - 1996/2/26

Y1 - 1996/2/26

N2 - The spirocyclic alkaloid (+)-isonitramine (1) has been synthesized in a stereoselective manner utilizing a novel 'triple allylic strain-controlled' intramolecular lactam enolate SN2' alkylation.

AB - The spirocyclic alkaloid (+)-isonitramine (1) has been synthesized in a stereoselective manner utilizing a novel 'triple allylic strain-controlled' intramolecular lactam enolate SN2' alkylation.

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U2 - 10.1016/0040-4039(96)00023-8

DO - 10.1016/0040-4039(96)00023-8

M3 - Article

AN - SCOPUS:0030001954

SN - 0040-4039

VL - 37

SP - 1433

EP - 1434

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 9

ER -

An asymmetric synthesis of (+)-isonitramine by 'triple allylic strain-controlled' intramolecular S_N2' alkylation

Abstract

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