Bismuth tungstate-anchored PEDOT: PSS materials for high performance HER electrocatalyst

Ramalingam Manikandan; Sankar Sekar; S. Pugal Mani; Sejoon Lee; Deuk Young Kim; S. Saravanan

doi:10.1016/j.ijhydene.2023.01.085

Bismuth tungstate-anchored PEDOT: PSS materials for high performance HER electrocatalyst

Ramalingam Manikandan, Sankar Sekar, S. Pugal Mani, Sejoon Lee, Deuk Young Kim, S. Saravanan

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Bismuth tungstate anchored PEDOT: PSS (BiW@PEPS) electrocatalyst was prepared via hydrothermal and ultrasonication methods successively. The synergetic effects of bismuth tungstate with PEDOT: PSS conducting polymer showed excellent electrocatalytic performance of hydrogen evolution reactions (HER) in alkaline conditions. When compared with pristine bismuth tungstate, the BiW@PEPS exhibited an enhanced electrocatalytic activity with a lower overpotential of 361 mV at 10 mA cm⁻², small Tafel slope of 106 mV/dec and enduring stability in 1 M KOH electrolyte. The enhanced electrocatalytic performance of the BiW@PEPS proved to be a beneficial electrocatalyst to the high-cost platinum-based materials in hydrogen production applications.

Original language	English
Pages (from-to)	11746-11753
Number of pages	8
Journal	International Journal of Hydrogen Energy
Volume	48
Issue number	31
DOIs	https://doi.org/10.1016/j.ijhydene.2023.01.085
State	Published - 12 Apr 2023

Keywords

Bismuth tungstate
Electrocatalyst
Hydrogen evolution reaction
PEDOT
PSS
Synergetic effect

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2023.01.085

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@article{44e54ff5a26840e3a9e371eb7b8b855f,

title = "Bismuth tungstate-anchored PEDOT: PSS materials for high performance HER electrocatalyst",

abstract = "Bismuth tungstate anchored PEDOT: PSS (BiW@PEPS) electrocatalyst was prepared via hydrothermal and ultrasonication methods successively. The synergetic effects of bismuth tungstate with PEDOT: PSS conducting polymer showed excellent electrocatalytic performance of hydrogen evolution reactions (HER) in alkaline conditions. When compared with pristine bismuth tungstate, the BiW@PEPS exhibited an enhanced electrocatalytic activity with a lower overpotential of 361 mV at 10 mA cm−2, small Tafel slope of 106 mV/dec and enduring stability in 1 M KOH electrolyte. The enhanced electrocatalytic performance of the BiW@PEPS proved to be a beneficial electrocatalyst to the high-cost platinum-based materials in hydrogen production applications.",

keywords = "Bismuth tungstate, Electrocatalyst, Hydrogen evolution reaction, PEDOT, PSS, Synergetic effect",

author = "Ramalingam Manikandan and Sankar Sekar and Mani, {S. Pugal} and Sejoon Lee and Kim, {Deuk Young} and S. Saravanan",

note = "Publisher Copyright: {\textcopyright} 2023 Hydrogen Energy Publications LLC",

year = "2023",

month = apr,

day = "12",

doi = "10.1016/j.ijhydene.2023.01.085",

language = "English",

volume = "48",

pages = "11746--11753",

journal = "International Journal of Hydrogen Energy",

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number = "31",

}

TY - JOUR

T1 - Bismuth tungstate-anchored PEDOT

T2 - PSS materials for high performance HER electrocatalyst

AU - Manikandan, Ramalingam

AU - Sekar, Sankar

AU - Mani, S. Pugal

AU - Lee, Sejoon

AU - Kim, Deuk Young

AU - Saravanan, S.

PY - 2023/4/12

Y1 - 2023/4/12

N2 - Bismuth tungstate anchored PEDOT: PSS (BiW@PEPS) electrocatalyst was prepared via hydrothermal and ultrasonication methods successively. The synergetic effects of bismuth tungstate with PEDOT: PSS conducting polymer showed excellent electrocatalytic performance of hydrogen evolution reactions (HER) in alkaline conditions. When compared with pristine bismuth tungstate, the BiW@PEPS exhibited an enhanced electrocatalytic activity with a lower overpotential of 361 mV at 10 mA cm−2, small Tafel slope of 106 mV/dec and enduring stability in 1 M KOH electrolyte. The enhanced electrocatalytic performance of the BiW@PEPS proved to be a beneficial electrocatalyst to the high-cost platinum-based materials in hydrogen production applications.

AB - Bismuth tungstate anchored PEDOT: PSS (BiW@PEPS) electrocatalyst was prepared via hydrothermal and ultrasonication methods successively. The synergetic effects of bismuth tungstate with PEDOT: PSS conducting polymer showed excellent electrocatalytic performance of hydrogen evolution reactions (HER) in alkaline conditions. When compared with pristine bismuth tungstate, the BiW@PEPS exhibited an enhanced electrocatalytic activity with a lower overpotential of 361 mV at 10 mA cm−2, small Tafel slope of 106 mV/dec and enduring stability in 1 M KOH electrolyte. The enhanced electrocatalytic performance of the BiW@PEPS proved to be a beneficial electrocatalyst to the high-cost platinum-based materials in hydrogen production applications.

KW - Bismuth tungstate

KW - Electrocatalyst

KW - Hydrogen evolution reaction

KW - PEDOT

KW - PSS

KW - Synergetic effect

UR - http://www.scopus.com/inward/record.url?scp=85147293871&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2023.01.085

DO - 10.1016/j.ijhydene.2023.01.085

M3 - Article

AN - SCOPUS:85147293871

SN - 0360-3199

VL - 48

SP - 11746

EP - 11753

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 31

ER -

Bismuth tungstate-anchored PEDOT: PSS materials for high performance HER electrocatalyst

Abstract

Keywords

UN SDGs

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