Abstract
Traditional synthetic routes for transition metal sulfides typically involve solution and thermal-based processes to exploit their favorable pseudo-capacitive properties. However, there is a practical need to develop alternative processes to fabricate metal sulfide electrodes because of the time-consuming processes (>12 h), additional heat-treatment to active reactants, relatively high post-heat-treatment temperature (200-400 °C) and non-scalable nature of existing synthetic routes. Herein, utilizing a solution-based sulfur precursor, one-dimensional single-crystalline Cu 2 S nanostructures have been successfully prepared via a solution-based direct synthesis process within 10 min at room temperature without the need for thermal treatment steps. The fabricated electrode exhibits a capacitance of 750 mF cm -2 at a current density of 2 mA cm -2 . Moreover, the rate capacitance is maintained at about 82.3% as the current density is increased to 40 mA cm -2 , and the capacity retains 90.5% of the initial value after 20000 cycles. Importantly, as this method involves a solution-based formulation it is compatible with roll-to-roll processes, which is promising for mass and scalable production of the electrodes. The synthetic method ensures a facile and efficient approach to fabricating scalable one-dimensional single crystalline Cu 2 S nanostructures, highlighting the uniqueness of the solution-based sulfur activation method.
Original language | English |
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Pages (from-to) | 2529-2535 |
Number of pages | 7 |
Journal | Journal of Materials Chemistry A |
Volume | 7 |
Issue number | 6 |
DOIs | |
State | Published - 2019 |