Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

Dongbing Zhao; Ju Hyun Kim; Linda Stegemann; Cristian A. Strassert; Frank Glorius

doi:10.1002/anie.201411994

Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

Dongbing Zhao
, Ju Hyun Kim
, Linda Stegemann
, Cristian A. Strassert
, Frank Glorius

Department of Chemistry

University of Münster

Research output: Contribution to journal › Article › peer-review

314 Scopus citations

Abstract

The first highly efficient and scalable cobalt-catalyzed directed C-H functionalization with carbene precursors is presented. This methodology provides a modular route towards a new class of conjugated polycyclic hydrocarbons with tunable emission wavelengths both in solution and in the solid state.

Original language	English
Pages (from-to)	4508-4511
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	15
DOIs	https://doi.org/10.1002/anie.201411994
State	Published - 7 Apr 2015

Keywords

C-H activation
carbenes
cobalt
heterocycles
π-systems

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10.1002/anie.201411994

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title = "Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems",

abstract = "The first highly efficient and scalable cobalt-catalyzed directed C-H functionalization with carbene precursors is presented. This methodology provides a modular route towards a new class of conjugated polycyclic hydrocarbons with tunable emission wavelengths both in solution and in the solid state.",

keywords = "C-H activation, carbenes, cobalt, heterocycles, π-systems",

author = "Dongbing Zhao and Kim, \{Ju Hyun\} and Linda Stegemann and Strassert, \{Cristian A.\} and Frank Glorius",

note = "Publisher Copyright: {\textcopyright} 2015 Wiley-VCH Verlag GmbH \& Co. KGaA.",

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T2 - Straightforward Access towards Extended π-Systems

AU - Zhao, Dongbing

AU - Kim, Ju Hyun

AU - Stegemann, Linda

AU - Strassert, Cristian A.

AU - Glorius, Frank

PY - 2015/4/7

Y1 - 2015/4/7

N2 - The first highly efficient and scalable cobalt-catalyzed directed C-H functionalization with carbene precursors is presented. This methodology provides a modular route towards a new class of conjugated polycyclic hydrocarbons with tunable emission wavelengths both in solution and in the solid state.

AB - The first highly efficient and scalable cobalt-catalyzed directed C-H functionalization with carbene precursors is presented. This methodology provides a modular route towards a new class of conjugated polycyclic hydrocarbons with tunable emission wavelengths both in solution and in the solid state.

KW - C-H activation

KW - carbenes

KW - cobalt

KW - heterocycles

KW - π-systems

UR - https://www.scopus.com/pages/publications/84926393533

U2 - 10.1002/anie.201411994

DO - 10.1002/anie.201411994

M3 - Article

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SN - 1433-7851

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SP - 4508

EP - 4511

JO - Angewandte Chemie - International Edition

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IS - 15

ER -

Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

Abstract

Keywords

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