Colorimetric detection of Cu2+ based on the formation of peptide-copper complexes on silver nanoparticle surfaces

Gajanan Sampatrao Ghodake; Surendra Krishna Shinde; Rijuta Ganesh Saratale; Avinash Ashok Kadam; Ganesh Dattatraya Saratale; Asad Syed; Fuad Ameen; Dae Young Kim

doi:10.3762/bjnano.9.134

Colorimetric detection of Cu²⁺ based on the formation of peptide-copper complexes on silver nanoparticle surfaces

Gajanan Sampatrao Ghodake
, Surendra Krishna Shinde
, Rijuta Ganesh Saratale
, Avinash Ashok Kadam
, Ganesh Dattatraya Saratale
, Asad Syed
, Fuad Ameen
, Dae Young Kim

Dongguk University
King Saud University

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

We developed a colorimetric method for the rapid detection of copper ions (Cu²⁺) in aqueous solution. The detection of Cu²⁺ is based on coordination reactions of Cu²⁺ with casein peptide-functionalized silver nanoparticles (AgNPs), leading to a distinct color change of the solution from yellow to red. The developed method has a good detection limit of about 0.16 μM Cu²⁺ using 0.05 mL of AgNPs stock solution and a linearity in the range of 0.08-1.44 μM Cu²⁺ with a correlation coefficient of R2 = 0.973. The developed method is a useful tool for the detection of Cu²⁺ ions. Furthermore, it can be used for monitoring Cu²⁺ in water at concentrations below the safe limit for drinking water set by the World Health Organization.

Original language	English
Pages (from-to)	1414-1422
Number of pages	9
Journal	Beilstein Journal of Nanotechnology
Volume	9
Issue number	1
DOIs	https://doi.org/10.3762/bjnano.9.134
State	Published - 2018

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 6 Clean Water and Sanitation

Keywords

Absorbance
Dispersion
Drinking water
Rapid detection
UV spectroscopy

Access to Document

10.3762/bjnano.9.134

Cite this

@article{137f7da760f94666ae32c2904d736001,

title = "Colorimetric detection of Cu2+ based on the formation of peptide-copper complexes on silver nanoparticle surfaces",

abstract = "We developed a colorimetric method for the rapid detection of copper ions (Cu2+) in aqueous solution. The detection of Cu2+ is based on coordination reactions of Cu2+ with casein peptide-functionalized silver nanoparticles (AgNPs), leading to a distinct color change of the solution from yellow to red. The developed method has a good detection limit of about 0.16 μM Cu2+ using 0.05 mL of AgNPs stock solution and a linearity in the range of 0.08-1.44 μM Cu2+ with a correlation coefficient of R2 = 0.973. The developed method is a useful tool for the detection of Cu2+ ions. Furthermore, it can be used for monitoring Cu2+ in water at concentrations below the safe limit for drinking water set by the World Health Organization.",

keywords = "Absorbance, Dispersion, Drinking water, Rapid detection, UV spectroscopy",

author = "Ghodake, \{Gajanan Sampatrao\} and Shinde, \{Surendra Krishna\} and Saratale, \{Rijuta Ganesh\} and Kadam, \{Avinash Ashok\} and Saratale, \{Ganesh Dattatraya\} and Asad Syed and Fuad Ameen and Kim, \{Dae Young\}",

note = "Publisher Copyright: {\textcopyright} 2018 Ghodake et al.",

year = "2018",

doi = "10.3762/bjnano.9.134",

language = "English",

volume = "9",

pages = "1414--1422",

journal = "Beilstein Journal of Nanotechnology",

issn = "2190-4286",

publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

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TY - JOUR

T1 - Colorimetric detection of Cu2+ based on the formation of peptide-copper complexes on silver nanoparticle surfaces

AU - Ghodake, Gajanan Sampatrao

AU - Shinde, Surendra Krishna

AU - Saratale, Rijuta Ganesh

AU - Kadam, Avinash Ashok

AU - Saratale, Ganesh Dattatraya

AU - Syed, Asad

AU - Ameen, Fuad

AU - Kim, Dae Young

PY - 2018

Y1 - 2018

N2 - We developed a colorimetric method for the rapid detection of copper ions (Cu2+) in aqueous solution. The detection of Cu2+ is based on coordination reactions of Cu2+ with casein peptide-functionalized silver nanoparticles (AgNPs), leading to a distinct color change of the solution from yellow to red. The developed method has a good detection limit of about 0.16 μM Cu2+ using 0.05 mL of AgNPs stock solution and a linearity in the range of 0.08-1.44 μM Cu2+ with a correlation coefficient of R2 = 0.973. The developed method is a useful tool for the detection of Cu2+ ions. Furthermore, it can be used for monitoring Cu2+ in water at concentrations below the safe limit for drinking water set by the World Health Organization.

AB - We developed a colorimetric method for the rapid detection of copper ions (Cu2+) in aqueous solution. The detection of Cu2+ is based on coordination reactions of Cu2+ with casein peptide-functionalized silver nanoparticles (AgNPs), leading to a distinct color change of the solution from yellow to red. The developed method has a good detection limit of about 0.16 μM Cu2+ using 0.05 mL of AgNPs stock solution and a linearity in the range of 0.08-1.44 μM Cu2+ with a correlation coefficient of R2 = 0.973. The developed method is a useful tool for the detection of Cu2+ ions. Furthermore, it can be used for monitoring Cu2+ in water at concentrations below the safe limit for drinking water set by the World Health Organization.

KW - Absorbance

KW - Dispersion

KW - Drinking water

KW - Rapid detection

KW - UV spectroscopy

UR - https://www.scopus.com/pages/publications/85047141472

U2 - 10.3762/bjnano.9.134

DO - 10.3762/bjnano.9.134

M3 - Article

AN - SCOPUS:85047141472

SN - 2190-4286

VL - 9

SP - 1414

EP - 1422

JO - Beilstein Journal of Nanotechnology

JF - Beilstein Journal of Nanotechnology

IS - 1

ER -