Correlative structural refinement-magnetic tunability, and enhanced magnetostriction in low-temperature, microwave-annealed, Ni-substituted CoFe2O4 nanoparticles

Sagar M. Mane, Aviraj M. Teli, Nishant T. Tayade, Kanchan J. Pawar, Shrinivas B. Kulkarni, Jonghyeon Choi, Jung Woo Yoo, Jae Cheol Shin

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The preparation of nanomaterials by conventional methods involves multiple steps that are time- and energy-consuming; hence, it must be replaced by clean, environment-friendly processes. Nanostructured mixed spinel ferrites have wide applicability given their electrical, magnetic, and magnetostrictive properties. Herein, we present an ultrafast, eco-friendly, and thermally efficient microwave (MW)-heating technique to replace the conventional strategies for the preparation of Ni-doped CoFe2O4 ferrite nanoparticles. Mixed spinel ferrite nanoparticles are obtained through an MW technique carried out for 20 min at 600 °C. The cubic nature of the MW-processed, Ni-substituted CoFe2O4 spinel ferrite is demonstrated by Rietveld refinement. Composition-dependent tunable magnetic properties associated with cation distribution and average crystallite size variation are realized by the substitution of Ni2+ at Co2+ in the CoFe2O4 lattice. The highest values of saturation magnetization and coercivity are noted for the Co0.9Ni0.1Fe2O4 ferrite at 5 K and the average crystallite size is ~ 20 nm; the octa to tetra transition of Co2+ is observed owing to substitution by Ni2+ ions. The highest values of magnetostrictive coefficient and strain sensitivity are detected for CoFe2O4; the Ni2+-substituted Co0.9Ni0.1Fe2O4 also exhibits nearly identical behavior. Thus, Ni2+-substituted CoFe2O4 is a remarkable magnetostrictive material suitable for developing magnetoelectric composites and magneto-mechanical sensor applications. Moreover, it is observed that efficient, fast, and eco-friendly microwave processing can be adopted as an alternative approach for low-temperature processing such kinds of nanostructured materials for future electromagnetic device applications.

Original languageEnglish
Article number162627
JournalJournal of Alloys and Compounds
Volume895
DOIs
StatePublished - 25 Feb 2022

Keywords

  • Cation distribution
  • Magneto-mechanical properties
  • Microwave processing
  • Mixed spinel ferrite
  • Tunable magnetic properties

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