Defect emission photoluminescence peak tuning by encapsulation of Au-NPs on ZnO mesoporous nanosponges

Sanjeev K. Sharma, Km Preeti, Gaurav Sharma, Rinku Gupta, Gajanan S. Ghodake, Arun Vir Singh

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

We synthesized Au nanoparticles (Au-NPs) encapsulated zinc oxide (ZnO:Au) nanosponges by the fraternization of ZnO nanoflowers with HCl (0–30 mM) concentrated colloidal Au-NPs at room temperature. The crystallite size (D) of mesoporous ZnO:Au decreased from 44 nm to 22 nm and the strain (τ) increased from 2.5 × 10−3 to 4.7 × 10−3 as the HCl concentration of colloidal Au-NPs increased from 0 mM to 30 mM. For elemental composition of ZnO:Au nanosponges, the STM-mapping confirmed the Au-NPs encapsulation on nanostructured ZnO. The bandgap, Eg, and the Urbach energy, Eu, of ZnO:Au decreased from 3.26 to 2.96 eV, and from 0.335 to 0.318 eV, as the colloidal Au-NPs increased from 0 mM to 30 mM, respectively. The structural and microstructure analysis showed the sponge like morphology along with wurtzite hexagonal structure of ZnO, which tuned the PL emission for the sensor selectivity. The visible emission of ZnO:Au nanosponges was greatly tuned from 600 nm to 500 nm with respect to the HCl diluted colloidal Au-NPs. The excellent photoluminescence (PL) performance of nanostructured ZnO:Au was attributed to the surface-plasmon-mediated sequential transfer of defect energy from ZnO to Au and electron transfer from excited Au to ZnO.

Original languageEnglish
Article number118695
JournalJournal of Luminescence
Volume244
DOIs
StatePublished - Apr 2022

Keywords

  • Defect emission photoluminescence and mechanism
  • Microstructural analysis
  • STM-Mapping
  • Synthesis of ZnO:Au nanosponges

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