TY - JOUR
T1 - Design of a Novel Process for Continuous Lactide Synthesis from Lactic Acid
AU - Park, Jinwoo
AU - Cho, Hyungtae
AU - Hwang, Dongwon
AU - Kim, Seungnam
AU - Moon, Il
AU - Kim, Myungjun
N1 - Publisher Copyright:
Copyright © 2018 American Chemical Society.
PY - 2018/9/5
Y1 - 2018/9/5
N2 - Lactide synthesis is an energy-intensive process used to produce polylactic acid (PLA). In this study, we propose a continuous lactide synthesis process developed on the basis of a recently developed one-step reaction using a SnO2-SiO2 nanocomposite catalyst. This process enables a rapid reaction time of 40 ms for the catalyst, which achieves 94% lactide yield. To design an efficient chemical process, reaction kinetics were developed and a heterogeneous reactor model was applied to the reactor. The proposed process has advantages over commercial processes, having both a rapid reaction rate and high yield. Moreover, its rapid reaction rate significantly increases the productivity. In addition, this process operates under atmospheric pressure, which makes it more energy efficient than commercial processes that operate under a high vacuum pressure of 20 mmHg. Therefore, the overall process is an effective alternative for lactide production.
AB - Lactide synthesis is an energy-intensive process used to produce polylactic acid (PLA). In this study, we propose a continuous lactide synthesis process developed on the basis of a recently developed one-step reaction using a SnO2-SiO2 nanocomposite catalyst. This process enables a rapid reaction time of 40 ms for the catalyst, which achieves 94% lactide yield. To design an efficient chemical process, reaction kinetics were developed and a heterogeneous reactor model was applied to the reactor. The proposed process has advantages over commercial processes, having both a rapid reaction rate and high yield. Moreover, its rapid reaction rate significantly increases the productivity. In addition, this process operates under atmospheric pressure, which makes it more energy efficient than commercial processes that operate under a high vacuum pressure of 20 mmHg. Therefore, the overall process is an effective alternative for lactide production.
UR - http://www.scopus.com/inward/record.url?scp=85052372930&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.8b02419
DO - 10.1021/acs.iecr.8b02419
M3 - Article
AN - SCOPUS:85052372930
SN - 0888-5885
VL - 57
SP - 11955
EP - 11962
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
IS - 35
ER -