Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe3O4 nanoparticles: kinetic and thermodynamic study

Suryakant A. Patil; Pramod D. Kumbhar; Sandip K. Patil; Madagonda M. Vadiyar; Umesh P. Suryawanshi; Chitra L. Jambhale; Mansing A. Anuse; Jin H. Kim; Sanjay S. Kolekar

doi:10.1080/03067319.2020.1734197

Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe₃O₄ nanoparticles: kinetic and thermodynamic study

Suryakant A. Patil, Pramod D. Kumbhar, Sandip K. Patil, Madagonda M. Vadiyar, Umesh P. Suryawanshi, Chitra L. Jambhale, Mansing A. Anuse, Jin H. Kim, Sanjay S. Kolekar

Department of Energy and Materials Engineering

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The bio-inspired synthesis of Fe₃O₄ nanoparticles using a common kitchen waste, Bengal gram bean (Cicer arietinum L.) extract (BGBE) for enhanced adsorption of toxic indigo carmine dye is reported. Synthesised adsorbent was characterised by FTIR, FE-SEM, XRD, BET and XPS to understand its meticulous properties. The Fe₃O₄ adsorbent shows fascinating surface area of 78.61 m² g⁻¹ with a pore volume of 0.25 cc g⁻¹ at P/P₀ = 0.98 and displayed nanograin like morphology. The efficiency towards adsorption of toxic IC dye was found up to 99.71 ± 0.35% within 40 min at pH 7 with 0.25 g of Fe₃O₄ nanomaterials having the 299 ± 2 K surrounding temperature. The Langmuir monolayer adsorption capacity was found to 393.7 mg g⁻¹ at the stroke speed 150 rpm. The experimental data follows the Freundlich adsorption isotherm. Kinetically the uptake rate of IC dye follows pseudo-second-order kinetic model. The thermodynamic study reveals that IC dye adsorption process is spontaneous and endothermic in nature.

Original language	English
Pages (from-to)	1205-1227
Number of pages	23
Journal	International Journal of Environmental Analytical Chemistry
Volume	102
Issue number	5
DOIs	https://doi.org/10.1080/03067319.2020.1734197
State	Published - 2022

Keywords

adsorption
Bengal gram bean (Cicer arietinum L.) extract
bio-inspired magnetic FeO
Freundlich isotherm
indigo carmine dye

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1080/03067319.2020.1734197

Cite this

Patil, S. A., Kumbhar, P. D., Patil, S. K., Vadiyar, M. M., Suryawanshi, U. P., Jambhale, C. L., Anuse, M. A., Kim, J. H., & Kolekar, S. S. (2022). Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe₃O₄ nanoparticles: kinetic and thermodynamic study. International Journal of Environmental Analytical Chemistry, 102(5), 1205-1227. https://doi.org/10.1080/03067319.2020.1734197

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title = "Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe3O4 nanoparticles: kinetic and thermodynamic study",

abstract = "The bio-inspired synthesis of Fe3O4 nanoparticles using a common kitchen waste, Bengal gram bean (Cicer arietinum L.) extract (BGBE) for enhanced adsorption of toxic indigo carmine dye is reported. Synthesised adsorbent was characterised by FTIR, FE-SEM, XRD, BET and XPS to understand its meticulous properties. The Fe3O4 adsorbent shows fascinating surface area of 78.61 m2 g−1 with a pore volume of 0.25 cc g−1 at P/P0 = 0.98 and displayed nanograin like morphology. The efficiency towards adsorption of toxic IC dye was found up to 99.71 ± 0.35% within 40 min at pH 7 with 0.25 g of Fe3O4 nanomaterials having the 299 ± 2 K surrounding temperature. The Langmuir monolayer adsorption capacity was found to 393.7 mg g−1 at the stroke speed 150 rpm. The experimental data follows the Freundlich adsorption isotherm. Kinetically the uptake rate of IC dye follows pseudo-second-order kinetic model. The thermodynamic study reveals that IC dye adsorption process is spontaneous and endothermic in nature.",

keywords = "adsorption, Bengal gram bean (Cicer arietinum L.) extract, bio-inspired magnetic FeO, Freundlich isotherm, indigo carmine dye",

author = "Patil, {Suryakant A.} and Kumbhar, {Pramod D.} and Patil, {Sandip K.} and Vadiyar, {Madagonda M.} and Suryawanshi, {Umesh P.} and Jambhale, {Chitra L.} and Anuse, {Mansing A.} and Kim, {Jin H.} and Kolekar, {Sanjay S.}",

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year = "2022",

doi = "10.1080/03067319.2020.1734197",

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Patil, SA, Kumbhar, PD, Patil, SK, Vadiyar, MM, Suryawanshi, UP, Jambhale, CL, Anuse, MA, Kim, JH & Kolekar, SS 2022, 'Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe₃O₄ nanoparticles: kinetic and thermodynamic study', International Journal of Environmental Analytical Chemistry, vol. 102, no. 5, pp. 1205-1227. https://doi.org/10.1080/03067319.2020.1734197

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T1 - Dynamic adsorption of toxic indigo carmine dye on bio-inspired synthesised Fe3O4 nanoparticles

T2 - kinetic and thermodynamic study

AU - Patil, Suryakant A.

AU - Kumbhar, Pramod D.

AU - Patil, Sandip K.

AU - Vadiyar, Madagonda M.

AU - Suryawanshi, Umesh P.

AU - Jambhale, Chitra L.

AU - Anuse, Mansing A.

AU - Kim, Jin H.

AU - Kolekar, Sanjay S.

PY - 2022

Y1 - 2022

N2 - The bio-inspired synthesis of Fe3O4 nanoparticles using a common kitchen waste, Bengal gram bean (Cicer arietinum L.) extract (BGBE) for enhanced adsorption of toxic indigo carmine dye is reported. Synthesised adsorbent was characterised by FTIR, FE-SEM, XRD, BET and XPS to understand its meticulous properties. The Fe3O4 adsorbent shows fascinating surface area of 78.61 m2 g−1 with a pore volume of 0.25 cc g−1 at P/P0 = 0.98 and displayed nanograin like morphology. The efficiency towards adsorption of toxic IC dye was found up to 99.71 ± 0.35% within 40 min at pH 7 with 0.25 g of Fe3O4 nanomaterials having the 299 ± 2 K surrounding temperature. The Langmuir monolayer adsorption capacity was found to 393.7 mg g−1 at the stroke speed 150 rpm. The experimental data follows the Freundlich adsorption isotherm. Kinetically the uptake rate of IC dye follows pseudo-second-order kinetic model. The thermodynamic study reveals that IC dye adsorption process is spontaneous and endothermic in nature.

AB - The bio-inspired synthesis of Fe3O4 nanoparticles using a common kitchen waste, Bengal gram bean (Cicer arietinum L.) extract (BGBE) for enhanced adsorption of toxic indigo carmine dye is reported. Synthesised adsorbent was characterised by FTIR, FE-SEM, XRD, BET and XPS to understand its meticulous properties. The Fe3O4 adsorbent shows fascinating surface area of 78.61 m2 g−1 with a pore volume of 0.25 cc g−1 at P/P0 = 0.98 and displayed nanograin like morphology. The efficiency towards adsorption of toxic IC dye was found up to 99.71 ± 0.35% within 40 min at pH 7 with 0.25 g of Fe3O4 nanomaterials having the 299 ± 2 K surrounding temperature. The Langmuir monolayer adsorption capacity was found to 393.7 mg g−1 at the stroke speed 150 rpm. The experimental data follows the Freundlich adsorption isotherm. Kinetically the uptake rate of IC dye follows pseudo-second-order kinetic model. The thermodynamic study reveals that IC dye adsorption process is spontaneous and endothermic in nature.

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KW - bio-inspired magnetic FeO

KW - Freundlich isotherm

KW - indigo carmine dye

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