Abstract
The carbon-based composite materials prepared through green synthetic approach are attracting greater interest in electrochemical applications due to their sustainable nature. Herein, we developed Fe2O3 and Fe2O3@CNT composite materials via a green mechanochemical one-pot method. The as prepared composite materials were characterized by X-ray diffraction (XRD), energy dispersive X-Ray spectroscopy (EDS), field emission scanning microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM), and X-ray photoelectron spectroscopy (XPS), respectively. Incorporating Fe2O3 nanoparticles on CNT surface tunes its electronic structure as well increases active sites and thus enhance the oxygen evolution reaction (OER) performance. As a result, the fabricated Fe2O3@CNT is a highly effective and balanced electrocatalyst that delivers superior current density (j = 10 mA cm−2) at low overpotential (η = 270 mV) for OER compared with pristine Fe2O3 (η = 290 mV) in 1 M KOH. Further, Fe2O3@CNT electrocatalyst shows high long-term durability in 1 M KOH for 100 h, fulfilling all the advantageous viable standards for OER.
Original language | English |
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Pages (from-to) | 29081-29086 |
Number of pages | 6 |
Journal | Ceramics International |
Volume | 48 |
Issue number | 19 |
DOIs | |
State | Published - 1 Oct 2022 |
Keywords
- Electrocatalyst
- FeO@CNT
- Long-term durablity
- Oxygen evolution reaction