TY - JOUR
T1 - Fabrication of Ru loaded MgB2 with guar gum hybrid for photocatalytic degradation of crystal violet
AU - Palem, Ramasubba Reddy
AU - Bathula, Chinna
AU - Shimoga, Ganesh
AU - Lee, Soo Hong
AU - Ghfar, Ayman A.
AU - Sekar, Sankar
AU - Kim, Hyun Seok
AU - Seo, Young Soo
AU - Rabani, Iqra
N1 - Publisher Copyright:
© 2023
PY - 2023/12/31
Y1 - 2023/12/31
N2 - Today, dyes/pigment-based materials are confronting a serious issue in harming marine ecology. Annihilate these serious water pollutants using photoactive 2D nanohybrid catalysts showed promising comparativeness over available photocatalysts. In the present work, a facile route to decorate Ruthenium (Ru) on 2D MgB2 flower-like nanostructures was developed via ecofriendly guar gum biopolymer substantial template (MgB2/GG@Ru NFS) and its photocatalytic performance was reported. Synthesis of MgB2@Ru, MgB2/GG@Ru NFS and commercial MgB2, was studied by FTIR, XRD, FE-SEM, EDX, AFM, TEM, UV–vis spectra, and XPS analysis. From the results, the MgB2/GG@Ru NFS exhibited a superior photocatalytic performance (99.7 %) than its precursors MgB2@Ru (79.7 %), and MgB2 (53.7 %), with the degradation efficiency of the crystal violet (CV) within 100 min under visible light irradiation. The proposed photo-catalyst MgB2/GG@Ru NFS showed negligible loss of photocatalytic activity even after five successive cycles, revealing its reusability and enhanced stability due to the network structure. The photocatalytic mechanism for MgB2/GG@Ru NFS was evaluated by trapping experiment of active species, verifying that superoxide ([rad]O2 −) and electron (e−) contributed significant role in the dye degradation.
AB - Today, dyes/pigment-based materials are confronting a serious issue in harming marine ecology. Annihilate these serious water pollutants using photoactive 2D nanohybrid catalysts showed promising comparativeness over available photocatalysts. In the present work, a facile route to decorate Ruthenium (Ru) on 2D MgB2 flower-like nanostructures was developed via ecofriendly guar gum biopolymer substantial template (MgB2/GG@Ru NFS) and its photocatalytic performance was reported. Synthesis of MgB2@Ru, MgB2/GG@Ru NFS and commercial MgB2, was studied by FTIR, XRD, FE-SEM, EDX, AFM, TEM, UV–vis spectra, and XPS analysis. From the results, the MgB2/GG@Ru NFS exhibited a superior photocatalytic performance (99.7 %) than its precursors MgB2@Ru (79.7 %), and MgB2 (53.7 %), with the degradation efficiency of the crystal violet (CV) within 100 min under visible light irradiation. The proposed photo-catalyst MgB2/GG@Ru NFS showed negligible loss of photocatalytic activity even after five successive cycles, revealing its reusability and enhanced stability due to the network structure. The photocatalytic mechanism for MgB2/GG@Ru NFS was evaluated by trapping experiment of active species, verifying that superoxide ([rad]O2 −) and electron (e−) contributed significant role in the dye degradation.
KW - Dye degradation
KW - Guar gum
KW - MgB
KW - Photocatalyst
KW - Ruthenium
KW - Stability-reusability
UR - http://www.scopus.com/inward/record.url?scp=85171391638&partnerID=8YFLogxK
U2 - 10.1016/j.ijbiomac.2023.126948
DO - 10.1016/j.ijbiomac.2023.126948
M3 - Article
C2 - 37722634
AN - SCOPUS:85171391638
SN - 0141-8130
VL - 253
JO - International Journal of Biological Macromolecules
JF - International Journal of Biological Macromolecules
M1 - 126948
ER -
