FT-IR skeletal study of RBa2Cu3O7-y (R = Ln or Y) and Nd2-xCexCuO4 cuprate powders

Marco Daturi, Guido Busca, Edoardo Magnone, Maurizio Ferretti

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Abstract

The FT-IR/FT-FIR spectra of powders of Nd2-xCexCuO4 solid solutions (x ≤ 0.25) and of RBa2Cu3O7-y (y = 0.2-0.3) with R = Y, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, and Yb, have been recorded at room temperature. A comparison with the published single crystal IR data is made. An empirical assignment of the observed bands is proposed on the basis of the factor group analysis and a discussion of the internal vibrational structure of the CuOx structures is given.

Original languageEnglish
Pages (from-to)36-44
Number of pages9
JournalJournal of Solid State Chemistry
Volume119
Issue number1
DOIs
StatePublished - Oct 1995

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