Gram-scale microwave-assisted synthesis of high-quality CsPbBr3 nanocrystals for optoelectronic applications

Sangeun Cho, Seongsu Hong, Atanu Jana, Inah Han, Hyungsang Kim, Hyunsik Im

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Fully inorganic halide perovskite nanocrystals (NCs) are promising candidates for optoelectronic applications due to their beneficial properties such as their amenability to solution processing, high absorption coefficients, and high quantum yields. Various methods have been developed to prepare perovskite CsPbX3 (X = Cl, Br, and I) NCs; however, large-scale synthesis with high-quality CsPbX3 NCs remains challenging. In the study, we report an advanced method for the gram-scale synthesis of all-inorganic perovskite NCs via specially designed microwave-assisted synthesis, which offers uniform reaction energy transfer, excellent reproducibility, and flexible parameter tuning. The composition, size and uniformity of the CsPbBr3 NCs have been optimized by controlling the surfactant ratio, precursor ratio, and reaction time. This systematic optimization leads to the production of gram-scale (> 0.165 g per a 100 ml reaction mixture for a single synthesis cycle) high-quality, phase-pure CsPbBr3 NCs with a uniform size of ∼ 10 nm. These optimized NCs exhibit a sharp photoluminescence peak centered at 515 nm with a photoluminescence quantum yield of 94 % and produce excellent radioluminescence under X-ray irradiation. To test the feasibility of these NCs for use in real optoelectronic devices, a photodetector consisting of CsPbBr3 NCs and monolayer MoS2 was fabricated, demonstrating enhanced photosensitivity and a faster response time compared with a pure MoS2-based photodetector. The proposed gram-scale microwave-assisted synthesis method thus has the potential to promote the commercialization of metal halide perovskite NCs through cost-effective mass production for use in many optoelectronic applications.

Original languageEnglish
Article number174700
JournalJournal of Alloys and Compounds
Volume993
DOIs
StatePublished - 25 Jul 2024

Keywords

  • Mass production
  • Microwave-assisted synthesis
  • Perovskite nanocrystals
  • Photodetector
  • Scintillator

Fingerprint

Dive into the research topics of 'Gram-scale microwave-assisted synthesis of high-quality CsPbBr3 nanocrystals for optoelectronic applications'. Together they form a unique fingerprint.

Cite this