Highly efficient surface sequestration of Pb²⁺ and Cr³⁺ from water using a Mn₃O₄ anchored reduced graphene oxide: Selective removal of Pb²⁺ from real water

Owing to the ubiquitous existence of detrimental heavy metals in the environment, simple adsorption-oriented approaches are becoming increasingly appealing for the effective removal of Pb²⁺ and Cr³⁺ from water bodies. These techniques use nanocomposites (NC) of reduced graphene oxide (rGO) and Mn₃O₄ (rGO-Mn₃O₄), they employ a hydrothermal technique featuring NaBH₄ and NaOH solutions. Here, spectroscopic and microscopic instrumental techniques were used to evaluate the morphological and physicochemical characteristics of prepared reduced graphene oxide manganese oxide (rGO-Mn₃O₄), revealing that it possessed a well-defined porous structure with a specific surface area of 126 m² g⁻¹. The prepared rGO-Mn₃O₄ had significant adsorption efficiencies for Pb²⁺ and Cr³⁺, achieving maximum sequestration capacities of 130.28 and 138.51 mg g⁻¹ for Pb²⁺ and Cr³⁺, respectively, according to the Langmuir model. These adsorption capacities are comparable to or greater than those of previously reported graphene-based materials. The Langmuir isotherm and pseudo-second-order models adequately represented the experimental results. Thermodynamic analysis revealed that adsorption occurred through spontaneous endothermic reactions. Recycling studies showed that the developed r-GO-Mn₃O₄ had excellent recyclability, with <70% removal at the 5th cycle; its feasibility was evaluated using industrial wastewater, suggesting that Pb²⁺ was selectively removed from Pb²⁺ and Cr³⁺ contaminated water. The instrumental analysis and surface phenomena studies presented here revealed that the adsorptive removal processes of both heavy metals involved π electron donor-acceptor interactions, ion exchange, and electrostatic interactions, along with surface complexation. Overall, the developed rGO-Mn₃O₄ has the potential to be a high-value adsorbent for removing heavy metals.