Hydrogen Permeation Properties and Chemical Stability of Novel Pd-Free Alloy Membranes Based on the V-Y System

E. Magnone; S. I. Jeon; J. H. Park; E. Fleury

doi:10.1002/ceat.201100456

Hydrogen Permeation Properties and Chemical Stability of Novel Pd-Free Alloy Membranes Based on the V-Y System

E. Magnone, S. I. Jeon, J. H. Park, E. Fleury

Department of Chemical and Biochemical Engineering

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

No investigation has yet been accomplished to screen the yttrium-doped effects on vanadium-based metal membranes. Synthesis, hydrogen permeation properties, and chemical stability of a novel palladium (Pd)-coated V ₉₉Y ₁ alloy membrane are presented. Hydrogen permeation experiments have been performed to investigate the hydrogen transport properties through the Pd-coated V ₉₉Y ₁ alloy membrane in the pressure range of 1.5-3.0bar under pure hydrogen as well as H ₂-CO ₂ and H ₂-CO gas mixtures at 400°C. The maximum hydrogen permeation rate was ~32mLmin ^-1cm ^-2 for a 0.5mm thick membrane under pure hydrogen. The results offer new directions in the synthesis of novel non-Pd-based metal membranes for hydrogen separation in precombustion capture applications.

Original language	English
Pages (from-to)	469-472
Number of pages	4
Journal	Chemical Engineering and Technology
Volume	35
Issue number	3
DOIs	https://doi.org/10.1002/ceat.201100456
State	Published - Mar 2012

Keywords

Alloy membranes
Hydrogen permeation
Metal membranes
Precombustion capture

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title = "Hydrogen Permeation Properties and Chemical Stability of Novel Pd-Free Alloy Membranes Based on the V-Y System",

abstract = "No investigation has yet been accomplished to screen the yttrium-doped effects on vanadium-based metal membranes. Synthesis, hydrogen permeation properties, and chemical stability of a novel palladium (Pd)-coated V 99Y 1 alloy membrane are presented. Hydrogen permeation experiments have been performed to investigate the hydrogen transport properties through the Pd-coated V 99Y 1 alloy membrane in the pressure range of 1.5-3.0bar under pure hydrogen as well as H 2-CO 2 and H 2-CO gas mixtures at 400°C. The maximum hydrogen permeation rate was ~32mLmin -1cm -2 for a 0.5mm thick membrane under pure hydrogen. The results offer new directions in the synthesis of novel non-Pd-based metal membranes for hydrogen separation in precombustion capture applications.",

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AU - Magnone, E.

AU - Jeon, S. I.

AU - Park, J. H.

AU - Fleury, E.

PY - 2012/3

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AB - No investigation has yet been accomplished to screen the yttrium-doped effects on vanadium-based metal membranes. Synthesis, hydrogen permeation properties, and chemical stability of a novel palladium (Pd)-coated V 99Y 1 alloy membrane are presented. Hydrogen permeation experiments have been performed to investigate the hydrogen transport properties through the Pd-coated V 99Y 1 alloy membrane in the pressure range of 1.5-3.0bar under pure hydrogen as well as H 2-CO 2 and H 2-CO gas mixtures at 400°C. The maximum hydrogen permeation rate was ~32mLmin -1cm -2 for a 0.5mm thick membrane under pure hydrogen. The results offer new directions in the synthesis of novel non-Pd-based metal membranes for hydrogen separation in precombustion capture applications.

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KW - Hydrogen permeation

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KW - Precombustion capture

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Hydrogen Permeation Properties and Chemical Stability of Novel Pd-Free Alloy Membranes Based on the V-Y System

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Keywords

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