Influence of Mn incorporation on the supercapacitive properties of hybrid CuO/Cu(OH)2 electrodes

Surendra K. Shinde; Deepak P. Dubal; Gajanan S. Ghodake; Pedro Gomez-Romero; Sungyeol Kim; Vijay J. Fulari

doi:10.1039/c5ra01093d

Influence of Mn incorporation on the supercapacitive properties of hybrid CuO/Cu(OH)₂ electrodes

Surendra K. Shinde, Deepak P. Dubal, Gajanan S. Ghodake, Pedro Gomez-Romero, Sungyeol Kim, Vijay J. Fulari

Department of Biological and Environmental Science

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

Here, we are presenting the effect of Mn doping on the supercapacitive properties of CuO/Cu(OH)₂ hybrid electrodes. Briefly, Mn doped CuO/Cu(OH)₂ (Mn:CuO/Cu(OH)₂) thin films have been synthesized by a successive ionic layer adsorption and reaction (SILAR) method which are further characterized by different physiochemical techniques. Our results revealed the formation of hybrid CuO/Cu(OH)₂ thin films with significant morphological deviation through Mn doping. Moreover, considerable positive effect of Mn doping on the electrochemical properties of hybrid CuO/Cu(OH)₂ electrodes have been witnessed. Later, the results suggest that at 3% Mn doping in CuO/Cu(OH)₂ electrodes with nanoflower-like nanostructures exhibits the highest specific capacitance. The maximum specific capacitance achieved for a 3% Mn:CuO/Cu(OH)₂ hybrid electrode is 600 F g^-1 at 5 mV s^-1 in 1 M Na₂SO₄ electrolyte. Additionally, a Ragone plot confirms the potential of the Mn:CuO/Cu(OH)₂ hybrid electrode for electrical energy storage applications.

Original language	English
Pages (from-to)	30478-30484
Number of pages	7
Journal	RSC Advances
Volume	5
Issue number	39
DOIs	https://doi.org/10.1039/c5ra01093d
State	Published - 2015

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title = "Influence of Mn incorporation on the supercapacitive properties of hybrid CuO/Cu(OH)2 electrodes",

abstract = "Here, we are presenting the effect of Mn doping on the supercapacitive properties of CuO/Cu(OH)2 hybrid electrodes. Briefly, Mn doped CuO/Cu(OH)2 (Mn:CuO/Cu(OH)2) thin films have been synthesized by a successive ionic layer adsorption and reaction (SILAR) method which are further characterized by different physiochemical techniques. Our results revealed the formation of hybrid CuO/Cu(OH)2 thin films with significant morphological deviation through Mn doping. Moreover, considerable positive effect of Mn doping on the electrochemical properties of hybrid CuO/Cu(OH)2 electrodes have been witnessed. Later, the results suggest that at 3% Mn doping in CuO/Cu(OH)2 electrodes with nanoflower-like nanostructures exhibits the highest specific capacitance. The maximum specific capacitance achieved for a 3% Mn:CuO/Cu(OH)2 hybrid electrode is 600 F g-1 at 5 mV s-1 in 1 M Na2SO4 electrolyte. Additionally, a Ragone plot confirms the potential of the Mn:CuO/Cu(OH)2 hybrid electrode for electrical energy storage applications.",

author = "Shinde, {Surendra K.} and Dubal, {Deepak P.} and Ghodake, {Gajanan S.} and Pedro Gomez-Romero and Sungyeol Kim and Fulari, {Vijay J.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c5ra01093d",

language = "English",

volume = "5",

pages = "30478--30484",

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T1 - Influence of Mn incorporation on the supercapacitive properties of hybrid CuO/Cu(OH)2 electrodes

AU - Shinde, Surendra K.

AU - Dubal, Deepak P.

AU - Ghodake, Gajanan S.

AU - Gomez-Romero, Pedro

AU - Kim, Sungyeol

AU - Fulari, Vijay J.

PY - 2015

Y1 - 2015

N2 - Here, we are presenting the effect of Mn doping on the supercapacitive properties of CuO/Cu(OH)2 hybrid electrodes. Briefly, Mn doped CuO/Cu(OH)2 (Mn:CuO/Cu(OH)2) thin films have been synthesized by a successive ionic layer adsorption and reaction (SILAR) method which are further characterized by different physiochemical techniques. Our results revealed the formation of hybrid CuO/Cu(OH)2 thin films with significant morphological deviation through Mn doping. Moreover, considerable positive effect of Mn doping on the electrochemical properties of hybrid CuO/Cu(OH)2 electrodes have been witnessed. Later, the results suggest that at 3% Mn doping in CuO/Cu(OH)2 electrodes with nanoflower-like nanostructures exhibits the highest specific capacitance. The maximum specific capacitance achieved for a 3% Mn:CuO/Cu(OH)2 hybrid electrode is 600 F g-1 at 5 mV s-1 in 1 M Na2SO4 electrolyte. Additionally, a Ragone plot confirms the potential of the Mn:CuO/Cu(OH)2 hybrid electrode for electrical energy storage applications.

AB - Here, we are presenting the effect of Mn doping on the supercapacitive properties of CuO/Cu(OH)2 hybrid electrodes. Briefly, Mn doped CuO/Cu(OH)2 (Mn:CuO/Cu(OH)2) thin films have been synthesized by a successive ionic layer adsorption and reaction (SILAR) method which are further characterized by different physiochemical techniques. Our results revealed the formation of hybrid CuO/Cu(OH)2 thin films with significant morphological deviation through Mn doping. Moreover, considerable positive effect of Mn doping on the electrochemical properties of hybrid CuO/Cu(OH)2 electrodes have been witnessed. Later, the results suggest that at 3% Mn doping in CuO/Cu(OH)2 electrodes with nanoflower-like nanostructures exhibits the highest specific capacitance. The maximum specific capacitance achieved for a 3% Mn:CuO/Cu(OH)2 hybrid electrode is 600 F g-1 at 5 mV s-1 in 1 M Na2SO4 electrolyte. Additionally, a Ragone plot confirms the potential of the Mn:CuO/Cu(OH)2 hybrid electrode for electrical energy storage applications.

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DO - 10.1039/c5ra01093d

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VL - 5

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EP - 30484

JO - RSC Advances

JF - RSC Advances

IS - 39

ER -

Influence of Mn incorporation on the supercapacitive properties of hybrid CuO/Cu(OH)₂ electrodes

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