TY - JOUR
T1 - Investigation on mesoporous bimetallic tungstate nanostructure for high-performance solid- state supercapattery
AU - Prabhu, S.
AU - Balaji, C.
AU - Navaneethan, M.
AU - Selvaraj, M.
AU - Anandhan, N.
AU - Sivaganesh, D.
AU - Saravanakumar, S.
AU - Sivakumar, Periyasamy
AU - Ramesh, R.
N1 - Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2021/9/15
Y1 - 2021/9/15
N2 - Identification of electrode materials with excellent specific capacity and energy density are significant factors for the development of high-performance supercapattery device. Transition metal tungstate is an emerging electroactive material for supercapattery due to its excellent electrical conductivity and electrochemical properties. Herein, the mesoporous Ni(1−x)Co(x)WO4 nanomaterials were synthesized by a one-step hydrothermal method as an anode material for supercapattery. The apparent discrepancy in mesoporous structures was incited by varying the stoichiometric ratio of Ni/Co in the Ni(1−x)Co(x)WO4 system which lead to an increase in the electrochemical properties. Among the synthesized electrode materials, Ni0.5Co0.5WO4 electrode material delivers the high specific capacity of 634.55 Cg−1 at 1 Ag−1 with an excellent rate capability of 92% after 10,000 cycles at 10 Ag−1. The solid-state supercapattery constructed with Nio.5Co0.5WO4 and reduced graphene oxide as positive and negative electrodes, respectively. The device exhibits the maximum specific capacity of 134.70 Cg−1 at 0.5 Ag−1 and energy density of 56.12 Wh kg−1 at 500 W kg−1 with long-term cyclic stability (90% capacity retentively after 20,000 cycles). The high performance of this electrode material has been attributed to the synergetic effect between bimetallic (Ni and Co) redox centers, a mesoporous structure that provides a larger redox cites, rich electrical conductivity, shorter diffusion length, and faster electrochemical kinetic rates for electrochemical reactions.
AB - Identification of electrode materials with excellent specific capacity and energy density are significant factors for the development of high-performance supercapattery device. Transition metal tungstate is an emerging electroactive material for supercapattery due to its excellent electrical conductivity and electrochemical properties. Herein, the mesoporous Ni(1−x)Co(x)WO4 nanomaterials were synthesized by a one-step hydrothermal method as an anode material for supercapattery. The apparent discrepancy in mesoporous structures was incited by varying the stoichiometric ratio of Ni/Co in the Ni(1−x)Co(x)WO4 system which lead to an increase in the electrochemical properties. Among the synthesized electrode materials, Ni0.5Co0.5WO4 electrode material delivers the high specific capacity of 634.55 Cg−1 at 1 Ag−1 with an excellent rate capability of 92% after 10,000 cycles at 10 Ag−1. The solid-state supercapattery constructed with Nio.5Co0.5WO4 and reduced graphene oxide as positive and negative electrodes, respectively. The device exhibits the maximum specific capacity of 134.70 Cg−1 at 0.5 Ag−1 and energy density of 56.12 Wh kg−1 at 500 W kg−1 with long-term cyclic stability (90% capacity retentively after 20,000 cycles). The high performance of this electrode material has been attributed to the synergetic effect between bimetallic (Ni and Co) redox centers, a mesoporous structure that provides a larger redox cites, rich electrical conductivity, shorter diffusion length, and faster electrochemical kinetic rates for electrochemical reactions.
KW - Bimetallic tungstate
KW - Cyclic stability
KW - Mesoporous
KW - Supercapattery
UR - http://www.scopus.com/inward/record.url?scp=85105831278&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2021.160066
DO - 10.1016/j.jallcom.2021.160066
M3 - Article
AN - SCOPUS:85105831278
SN - 0925-8388
VL - 875
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
M1 - 160066
ER -