Mathematical modeling and simulations of stress mitigation by coating polycrystalline particles in lithium-ion batteries

N. Iqbal, J. Choi, S. F. Shah, C. Lee, S. Lee

Research output: Contribution to journalArticlepeer-review

Abstract

A chemo-mechanical model is developed to investigate the effects on the stress development of the coating of polycrystalline Ni-rich LiNixMnyCozO2 (x ⩾ 0.8) (NMC) particles with poly(3,4-ethylenedioxythiophene) (PEDOT). The simulation results show that the coating of primary NMC particles significantly reduces the stress generation by efficiently accommodating the volume change associated with the lithium diffusion, and the coating layer plays roles both as a cushion against the volume change and a channel for the lithium transport, promoting the lithium distribution across the secondary particles more homogeneously. Besides, the lower stiffness, higher ionic conductivity, and larger thickness of the coating layer improve the stress mitigation. This paper provides a mathematical framework for calculating the chemo-mechanical responses of anisotropic electrode materials and fundamental insights into how the coating of NMC active particles mitigates stress levels.

Original languageEnglish
Pages (from-to)947-962
Number of pages16
JournalApplied Mathematics and Mechanics (English Edition)
Volume45
Issue number6
DOIs
StatePublished - Jun 2024

Keywords

  • 74E10
  • 74F25
  • 74S05
  • coating
  • finite element simulation
  • lithium-ion battery (LIB)
  • Ni-rich LiNiMnCoO (x ⩾ 0.8) (NMC)
  • O241.82
  • O343.8
  • O646.541
  • polycrystalline particle

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