Mild, simple, and efficient method for N-formylation of secondary amines via Reimer-Tiemann reaction

Lokesh A. Shastri; Samundeeswari L. Shastri; Chinna D. Bathula; Mahantesha Basanagouda; Manohar V. Kulkarni

doi:10.1080/00397910903576644

Mild, simple, and efficient method for N-formylation of secondary amines via Reimer-Tiemann reaction

Lokesh A. Shastri, Samundeeswari L. Shastri, Chinna D. Bathula, Mahantesha Basanagouda, Manohar V. Kulkarni

Department of Electronics & Electrical Engineering

Karnatak University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A rapid and easy route for the N-formylation of secondary amines using chloroform and sodium ethoxide via dichlorocarbene by the Riemer-Tiemann reaction with excellent yield is reported.

Original language	English
Pages (from-to)	476-484
Number of pages	9
Journal	Synthetic Communications
Volume	41
Issue number	4
DOIs	https://doi.org/10.1080/00397910903576644
State	Published - Jan 2011

Keywords

Dichlorocarbene
N-formylation
Reimer-Tiemann
secondary amines
sodium ethoxide

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10.1080/00397910903576644

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title = "Mild, simple, and efficient method for N-formylation of secondary amines via Reimer-Tiemann reaction",

abstract = "A rapid and easy route for the N-formylation of secondary amines using chloroform and sodium ethoxide via dichlorocarbene by the Riemer-Tiemann reaction with excellent yield is reported.",

keywords = "Dichlorocarbene, N-formylation, Reimer-Tiemann, secondary amines, sodium ethoxide",

author = "Shastri, {Lokesh A.} and Shastri, {Samundeeswari L.} and Bathula, {Chinna D.} and Mahantesha Basanagouda and Kulkarni, {Manohar V.}",

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AU - Shastri, Lokesh A.

AU - Shastri, Samundeeswari L.

AU - Bathula, Chinna D.

AU - Basanagouda, Mahantesha

AU - Kulkarni, Manohar V.

PY - 2011/1

Y1 - 2011/1

N2 - A rapid and easy route for the N-formylation of secondary amines using chloroform and sodium ethoxide via dichlorocarbene by the Riemer-Tiemann reaction with excellent yield is reported.

AB - A rapid and easy route for the N-formylation of secondary amines using chloroform and sodium ethoxide via dichlorocarbene by the Riemer-Tiemann reaction with excellent yield is reported.

KW - Dichlorocarbene

KW - N-formylation

KW - Reimer-Tiemann

KW - secondary amines

KW - sodium ethoxide

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DO - 10.1080/00397910903576644

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VL - 41

SP - 476

EP - 484

JO - Synthetic Communications

JF - Synthetic Communications

IS - 4

ER -

Mild, simple, and efficient method for N-formylation of secondary amines via Reimer-Tiemann reaction

Abstract

Keywords

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