Molecular understanding of a π-conjugated polymer/solid-state ionic liquid complex as a highly sensitive and selective gas sensor

Katherine Stewart, Saurav Limbu, James Nightingale, Katia Pagano, Byoungwook Park, Soonil Hong, Kwanghee Lee, Sooncheol Kwon, Ji Seon Kim

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Electric-field driven chemical doping modulation in a blend of solution-processed organic semiconductors (OSCs) and solid-state ionic liquids (SSILs) in response to volatile organic compounds (VOCs) provides a new exciting opportunity to facilitate printable and low-power chemical gas sensors (chemiresistors). In order to fully exploit this opportunity, a fundamental understanding of the molecular-level interactions among the OSCs, SSILs, and VOC components during the device operation is urgently needed. Herein, we demonstrate a highly sensitive and selective VOC gas sensor using π-conjugated polymer (here, P3HT as a model homopolymer) and SSIL blends. A newly developed SSIL forms a semi-crystalline solid at room temperature. P3HT with high molecular weight and regioregularity allows an extremely well-interconnected network in blends desirable for efficient charge transport. In P3HT:SSIL blends, we identify electric-field driven strong chemical interactions between π-CP and SSIL to tune the electrical conductivity of the π-CP. The enlarged interfacial areas in blends and the solid-state nature of the SSIL ensure highly tunable electrochemical interactions between them, efficiently modulating the electrical conductivity of the π-CP further upon exposure to different polar and non-polar VOCs. Our results demonstrate the π-conjugated polymer/SSIL complex as a new highly sensitive and selective gas sensor and provide a key scientific understanding of its molecular-level operational mechanism critical for developing molecular sensors towards next generation noninvasive diagnostics.

Original languageEnglish
Pages (from-to)15268-15276
Number of pages9
JournalJournal of Materials Chemistry C
Volume8
Issue number43
DOIs
StatePublished - 21 Nov 2020

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