Nanostructured metal-doped Prussian blue thin film electrodes for efficient and stable electrochromic supercapacitors

Akbar I. Inamdar, Harish S. Chavan, Giho Shin, Jonghoon Han, Seungun Yeon, Sunjung Park, Supriya A. Patil, Nabeen K. Shrestha, Hyungsang Kim, Hyunsik Im

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The combined features of functional electronic devices have attracted significant attention because of high demand for promising energy technologies. Of particular interest are electrochromic (EC) supercapacitors, which can visually display the level of stored energy in real-time. Here, we demonstrate the EC energy storage properties of pure and doped Prussian blue (PB) thin films fabricated using electrodeposition. The pure PB films produced various colours at different potentials during their charging-discharging cycles, but they suffered from instability. To overcome this, we doped PB films with ruthenium (Ru), iridium (Ir), and molybdenum (Mo). Of the doped specimens, the Mo-doped PB films exhibited the most promising EC energy storage properties, with a specific capacity of 399.7 F g−1 at 1 A g−1, a colouration efficiency of 110.2 cm2 C−1, and an excellent optical density difference of 0.92. The Mo-doped PB films also demonstrated ultra-fast colouration and bleaching behaviour within 3.25 and 4.04 seconds, respectively. Our experimental findings suggest that Metal-doped PB films can be employed for practical application.

Original languageEnglish
Pages (from-to)17220-17229
Number of pages10
JournalInternational Journal of Energy Research
Volume46
Issue number12
DOIs
StatePublished - 10 Oct 2022

Keywords

  • electrochemistry
  • electrochromism
  • energy storage
  • Prussian blue
  • smart window
  • supercapacitor

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