Abstract
Metal fluoride cathode materials, which are cost-effective and have large theoretical capacities, can be used in lithium-ion batteries (LIBs) to reduce the cost of these batteries. However, they have intrinsically low electrical conductivity and high overpotential. Herein, we report a bottom-up approach to synthesize NiF2/porous carbon (NPC) nanocomposites using an ammonium fluoride (NH4F) treatment. In this process the nickel precursor in the porous carbon is fluorinated under the solventless condition without hazardous reagents; thus, lower toxicity and higher yield compared to those of traditional methods can be achieved. Furthermore, we demonstrate the formation mechanism of NiF2 according to the reaction temperature. As a cathode material for LIBs, NPC nanocomposites exhibit an outstanding initial reversible capacity of 830 mAh g−1 at a current density of 50 mA g−1 and excellent rate performance of 487 mAh g−1 at a high current density of 1000 mA g−1. These capacities are much larger than those of the intercalation-based cathodes. The successful preparation of NPC nanocomposites may facilitate the use of metal fluorides as LIB cathode materials.
Original language | English |
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Article number | 230935 |
Journal | Journal of Power Sources |
Volume | 521 |
DOIs | |
State | Published - 15 Feb 2022 |
Keywords
- Ammonium fluoride
- Cathode
- Lithium ion batteries
- Nanocomposites
- Nickel fluorides
- Porous carbon