Novel pure α-, β-, and mixed-phase α/β-Bi₂O₃ photocatalysts for enhanced organic dye degradation under both visible light and solar irradiation

Combining the pure α- and β-phases of bismuth oxide enhances its photocatalytic activity under both visible and solar irradiation. α-Bi₂O₃, β-Bi₂O_3, and α/β-Bi₂O₃ were synthesized by a solvothermal calcination method. The structural, optical, and morphological properties of the as-synthesized catalysts were analyzed using XRD, UV-DRS, XPS, SEM, TEM, and PL. The bandgaps of α/β-Bi₂O₃, α-Bi₂O₃, and β-Bi₂O₃ were calculated to be 2.59, 2.73, and 2.34 eV, respectively. The photocatalytic activities of the catalysts under visible and solar irradiation were examined by the degradation of carcinogenic reactive blue 198 and reactive black 5 dyes. The kinetic plots of the degradation reactions followed pseudo-first-order kinetics. α/β-Bi₂O₃ exhibited higher photocatalytic activity (∼99%) than α-Bi₂O₃ and β-Bi₂O₃ under visible and solar irradiation. The TOC and COD results confirmed the maximum degradation ability of α/β-Bi₂O₃, and the decolorization percentage remained above 90%, even after five cycles under visible irradiation. The photocatalytic dye degradation mechanism employed by α/β-Bi₂O₃ was proposed based on active species trapping experiments.