[Os3(CO)6(PMe3)3] (μ3-η2:η2:η2-C 60)[Re3(μ-H)3(CO)9]: A fullerene[60] coordinated to two different trinuclear clusters

Bo Keun Park; Chang Yeon Lee; Jaehoon Jung; Jung Hak Lim; Young Kyu Han; Chang Seop Hong; Joon T. Park

doi:10.1002/anie.200603882

[Os₃(CO)₆(PMe₃)₃] (μ₃-η²:η²:η²-C ₆₀)[Re₃(μ-H)₃(CO)₉]: A fullerene[60] coordinated to two different trinuclear clusters

Bo Keun Park
, Chang Yeon Lee
, Jaehoon Jung
, Jung Hak Lim
, Young Kyu Han
, Chang Seop Hong
, Joon T. Park

Department of Energy and Materials Engineering

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

(Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature ¹H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

Original language	English
Pages (from-to)	1436-1439
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	9
DOIs	https://doi.org/10.1002/anie.200603882
State	Published - 2007

Keywords

Cluster compounds
Density functional calculations
Fullerenes
Osmium
Rhenium

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10.1002/anie.200603882

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title = "[Os3(CO)6(PMe3)3] (μ3-η2:η2:η2-C 60)[Re3(μ-H)3(CO)9]: A fullerene[60] coordinated to two different trinuclear clusters",

abstract = "(Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.",

keywords = "Cluster compounds, Density functional calculations, Fullerenes, Osmium, Rhenium",

author = "Park, \{Bo Keun\} and Lee, \{Chang Yeon\} and Jaehoon Jung and Lim, \{Jung Hak\} and Han, \{Young Kyu\} and Hong, \{Chang Seop\} and Park, \{Joon T.\}",

year = "2007",

doi = "10.1002/anie.200603882",

language = "English",

volume = "46",

pages = "1436--1439",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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}

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T1 - [Os3(CO)6(PMe3)3] (μ3-η2:η2:η2-C 60)[Re3(μ-H)3(CO)9]

T2 - A fullerene[60] coordinated to two different trinuclear clusters

AU - Park, Bo Keun

AU - Lee, Chang Yeon

AU - Jung, Jaehoon

AU - Lim, Jung Hak

AU - Han, Young Kyu

AU - Hong, Chang Seop

AU - Park, Joon T.

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

AB - (Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

KW - Cluster compounds

KW - Density functional calculations

KW - Fullerenes

KW - Osmium

KW - Rhenium

UR - https://www.scopus.com/pages/publications/34247859313

U2 - 10.1002/anie.200603882

DO - 10.1002/anie.200603882

M3 - Article

C2 - 17226880

AN - SCOPUS:34247859313

SN - 1433-7851

VL - 46

SP - 1436

EP - 1439

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

[Os₃(CO)₆(PMe₃)₃] (μ₃-η²:η²:η²-C ₆₀)[Re₃(μ-H)₃(CO)₉]: A fullerene[60] coordinated to two different trinuclear clusters

Abstract

Keywords

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