Phase transition behavior of NaCrO2 during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy

Yong Ning Zhou; Jing Jing Ding; Kyung Wan Nam; Xiqian Yu; Seong Min Bak; Enyuan Hu; Jue Liu; Jianming Bai; Hong Li; Zheng Wen Fu; Xiao Qing Yang

doi:10.1039/c3ta12282d

Phase transition behavior of NaCrO₂ during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy

Yong Ning Zhou
, Jing Jing Ding
, Kyung Wan Nam
, Xiqian Yu
, Seong Min Bak
, Enyuan Hu
, Jue Liu
, Jianming Bai
, Hong Li
, Zheng Wen Fu
, Xiao Qing Yang

Department of Energy and Materials Engineering

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

The structural evolution of layered NaCrO₂ cathodes for sodium-ion batteries during charge was investigated using synchrotron-based in situ X-ray diffraction and ex situ X-ray absorption spectroscopy. Three solid solution phases with expanding 'c' and contracting 'a'/'b' lattice parameters were observed. The coordination changes of Cr and Na during sodium extraction were also studied.

Original language	English
Pages (from-to)	11130-11134
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	37
DOIs	https://doi.org/10.1039/c3ta12282d
State	Published - 7 Oct 2013

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title = "Phase transition behavior of NaCrO2 during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy",

abstract = "The structural evolution of layered NaCrO2 cathodes for sodium-ion batteries during charge was investigated using synchrotron-based in situ X-ray diffraction and ex situ X-ray absorption spectroscopy. Three solid solution phases with expanding 'c' and contracting 'a'/'b' lattice parameters were observed. The coordination changes of Cr and Na during sodium extraction were also studied.",

author = "Zhou, \{Yong Ning\} and Ding, \{Jing Jing\} and Nam, \{Kyung Wan\} and Xiqian Yu and Bak, \{Seong Min\} and Enyuan Hu and Jue Liu and Jianming Bai and Hong Li and Fu, \{Zheng Wen\} and Yang, \{Xiao Qing\}",

year = "2013",

month = oct,

day = "7",

doi = "10.1039/c3ta12282d",

language = "English",

volume = "1",

pages = "11130--11134",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Phase transition behavior of NaCrO2 during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy

AU - Zhou, Yong Ning

AU - Ding, Jing Jing

AU - Nam, Kyung Wan

AU - Yu, Xiqian

AU - Bak, Seong Min

AU - Hu, Enyuan

AU - Liu, Jue

AU - Bai, Jianming

AU - Li, Hong

AU - Fu, Zheng Wen

AU - Yang, Xiao Qing

PY - 2013/10/7

Y1 - 2013/10/7

N2 - The structural evolution of layered NaCrO2 cathodes for sodium-ion batteries during charge was investigated using synchrotron-based in situ X-ray diffraction and ex situ X-ray absorption spectroscopy. Three solid solution phases with expanding 'c' and contracting 'a'/'b' lattice parameters were observed. The coordination changes of Cr and Na during sodium extraction were also studied.

AB - The structural evolution of layered NaCrO2 cathodes for sodium-ion batteries during charge was investigated using synchrotron-based in situ X-ray diffraction and ex situ X-ray absorption spectroscopy. Three solid solution phases with expanding 'c' and contracting 'a'/'b' lattice parameters were observed. The coordination changes of Cr and Na during sodium extraction were also studied.

UR - https://www.scopus.com/pages/publications/84883299003

U2 - 10.1039/c3ta12282d

DO - 10.1039/c3ta12282d

M3 - Article

AN - SCOPUS:84883299003

SN - 2050-7488

VL - 1

SP - 11130

EP - 11134

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 37

ER -

Phase transition behavior of NaCrO₂ during sodium extraction studied by synchrotron-based X-ray diffraction and absorption spectroscopy

Abstract

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