TY - JOUR
T1 - Preparation and characterization of maleimide-polystyrene/SiO2-Al2O3 hybrid nanocomposites by an in situ sol-gel process and its antimicrobial activity
AU - Ramesh, S.
AU - Sivasamy, A.
AU - Rhee, K. Y.
AU - Park, S. J.
AU - Hui, D.
N1 - Publisher Copyright:
© 2015 Elsevier Ltd. All rights reserved.
PY - 2015/6/15
Y1 - 2015/6/15
N2 - Inorganic-organic nanocomposites have unlocked new opportunities in the design of innovative materials and compounds with enhanced and unique properties, based on soft chemistry. In the present study, a hybrid nanocomposite of maleimide-polystyrene (PSMA) with SiO2 and Al2O3 (PSMA-SA) was synthesized by means of the sol-gel approach in the presence of γ-aminotriethoxysilane (γ-APTES), in which tetraethoxysilane (TEOS) and aluminum isopropoxide (AIP) were used as precursors. The Michael reaction led to bonding between the PSMA and SiO2-Al2O3, giving a stable cross-linked network that prevented aggregation and mechanical mixing of the nanoparticles. XRD and FTIR analysis confirmed the effects of the coupling agent in promoting the Michael reaction. Thermal properties of the hybrid nanocomposites were tested through TGA and DSC. SEM, TEM and optical tests confirmed the controlled morphology and optical transparency of the composites. Additionally, the hybrid nanocomposites showed excellent solvent resistance and antimicrobial activity against pathogenic bacteria such as Bacillus cereus and Escherichia coli.
AB - Inorganic-organic nanocomposites have unlocked new opportunities in the design of innovative materials and compounds with enhanced and unique properties, based on soft chemistry. In the present study, a hybrid nanocomposite of maleimide-polystyrene (PSMA) with SiO2 and Al2O3 (PSMA-SA) was synthesized by means of the sol-gel approach in the presence of γ-aminotriethoxysilane (γ-APTES), in which tetraethoxysilane (TEOS) and aluminum isopropoxide (AIP) were used as precursors. The Michael reaction led to bonding between the PSMA and SiO2-Al2O3, giving a stable cross-linked network that prevented aggregation and mechanical mixing of the nanoparticles. XRD and FTIR analysis confirmed the effects of the coupling agent in promoting the Michael reaction. Thermal properties of the hybrid nanocomposites were tested through TGA and DSC. SEM, TEM and optical tests confirmed the controlled morphology and optical transparency of the composites. Additionally, the hybrid nanocomposites showed excellent solvent resistance and antimicrobial activity against pathogenic bacteria such as Bacillus cereus and Escherichia coli.
KW - A. Polymer-matrix composites (PMCs)
KW - D. Chemical analysis
KW - D. Electron microscopy
KW - D. Thermal analysis
UR - http://www.scopus.com/inward/record.url?scp=84922704678&partnerID=8YFLogxK
U2 - 10.1016/j.compositesb.2015.01.040
DO - 10.1016/j.compositesb.2015.01.040
M3 - Article
AN - SCOPUS:84922704678
SN - 1359-8368
VL - 75
SP - 167
EP - 175
JO - Composites Part B: Engineering
JF - Composites Part B: Engineering
ER -