Preparation of superhydrophobic, long-neck vase-like polymer surfaces

Polymer surfaces comprising nanopillars with various geometries were prepared by nanoimprinting the surface using anodic aluminium oxide templates. In particular, a simple fabrication method for long-neck vase-like stepped nanopillars was established, and the surface showed considerable enhancement in the water contact angle, for example from 95.7°to 150.6°for the polystyrene surface. This enhanced hydrophobicity could be explained by the desirable reduction in the area of the solid-liquid interface and reduced sticking between the nanopillars.