Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base: Insights from Hirshfeld surface analysis

Kinsuk Das; Pampi Pal; Anamika Dhara; Atanu Jana

Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base: Insights from Hirshfeld surface analysis

Kinsuk Das, Pampi Pal, Anamika Dhara, Atanu Jana

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2 Scopus citations

Abstract

The Hirshfeld surface area was evaluated for both the complexes [Zn3(L)2Cl6] (1) and [Cd(L)(H20)2](C104)2 (2) [L = N6 donor hexadentate Schiff base 2,4-bis[2-(pyridine-2-ylmethylidene)hydrazinyl]pyrimidine]. The Hirshfeld surface analysis quantify the rare Cl-Cl weak interaction in 1 and other molecular interactions e.g. CH, H-H, CC, Kn present in the solid state of both complexes 1 and 2.

Original language	English
Pages (from-to)	115-123
Number of pages	9
Journal	Journal of the Indian Chemical Society
Volume	93
Issue number	1
State	Published - Jan 2016

Keywords

Cl-Cl interaction
Hirshfeld surface analysis
Weak interactions
Zn11 and Cd11 complex

Cite this

@article{31e87cd781944c2fadcd2cb98caae6d7,

title = "Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base: Insights from Hirshfeld surface analysis",

abstract = "The Hirshfeld surface area was evaluated for both the complexes [Zn3(L)2Cl6] (1) and [Cd(L)(H20)2](C104)2 (2) [L = N6 donor hexadentate Schiff base 2,4-bis[2-(pyridine-2-ylmethylidene)hydrazinyl]pyrimidine]. The Hirshfeld surface analysis quantify the rare Cl-Cl weak interaction in 1 and other molecular interactions e.g. CH, H-H, CC, Kn present in the solid state of both complexes 1 and 2.",

keywords = "Cl-Cl interaction, Hirshfeld surface analysis, Weak interactions, Zn11 and Cd11 complex",

author = "Kinsuk Das and Pampi Pal and Anamika Dhara and Atanu Jana",

year = "2016",

month = jan,

language = "English",

volume = "93",

pages = "115--123",

journal = "Journal of the Indian Chemical Society",

issn = "0019-4522",

publisher = "Elsevier B.V.",

number = "1",

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Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base: Insights from Hirshfeld surface analysis. / Das, Kinsuk; Pal, Pampi; Dhara, Anamika et al.
In: Journal of the Indian Chemical Society, Vol. 93, No. 1, 01.2016, p. 115-123.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base

T2 - Insights from Hirshfeld surface analysis

AU - Das, Kinsuk

AU - Pal, Pampi

AU - Dhara, Anamika

AU - Jana, Atanu

PY - 2016/1

Y1 - 2016/1

N2 - The Hirshfeld surface area was evaluated for both the complexes [Zn3(L)2Cl6] (1) and [Cd(L)(H20)2](C104)2 (2) [L = N6 donor hexadentate Schiff base 2,4-bis[2-(pyridine-2-ylmethylidene)hydrazinyl]pyrimidine]. The Hirshfeld surface analysis quantify the rare Cl-Cl weak interaction in 1 and other molecular interactions e.g. CH, H-H, CC, Kn present in the solid state of both complexes 1 and 2.

AB - The Hirshfeld surface area was evaluated for both the complexes [Zn3(L)2Cl6] (1) and [Cd(L)(H20)2](C104)2 (2) [L = N6 donor hexadentate Schiff base 2,4-bis[2-(pyridine-2-ylmethylidene)hydrazinyl]pyrimidine]. The Hirshfeld surface analysis quantify the rare Cl-Cl weak interaction in 1 and other molecular interactions e.g. CH, H-H, CC, Kn present in the solid state of both complexes 1 and 2.

KW - Cl-Cl interaction

KW - Hirshfeld surface analysis

KW - Weak interactions

KW - Zn11 and Cd11 complex

UR - http://www.scopus.com/inward/record.url?scp=85028965416&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:85028965416

SN - 0019-4522

VL - 93

SP - 115

EP - 123

JO - Journal of the Indian Chemical Society

JF - Journal of the Indian Chemical Society

IS - 1

ER -

Quantifying intermolecular interaction of one trinuclear Zn11 and one mononuclear Cd11 complex of pyrimidine based hexadentate Schiff base: Insights from Hirshfeld surface analysis

Abstract

Keywords

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