Reduced graphene-oxide-encapsulated mos₂ /carbon nanofiber composite electrode for high-performance na-ion batteries

Sodium-ion batteries (SIBs) have been increasingly studied due to sodium (Na) being an inexpensive ionic resource (Na) and their battery chemistry being similar to that of current lithium-ion batteries (LIBs). However, SIBs have faced substantial challenges in developing high-performance anode materials that can reversibly store Na⁺ in the host structure. To address these challenges, molybdenum sulfide (MoS₂ )-based active materials have been considered as promising anodes, owing to the two-dimensional layered structure of MoS₂ for stably (de)inserting Na⁺ . Nevertheless, intrinsic issues of MoS₂ —such as low electronic conductivity and the loss of active S elements after a conversion reaction—have limited the viability of MoS₂ in practical SIBs. Here, we report MoS₂ embedded in carbon nanofibers encapsulated with a reduced graphene oxide (MoS₂ @CNFs@rGO) composite for SIB anodes. The MoS₂ @CNFs@rGO delivered a high capacity of 345.8 mAh g⁻¹ at a current density of 100 mA g⁻¹ for 90 cycles. The CNFs and rGO were synergistically taken into account for providing rapid pathways for electrons and preventing the dissolution of S sources during repetitive conversion reactions. This work offers a new point of view to realize MoS₂-based anode materials in practical SIBs.