RhIII-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

Ju Hyun Kim, Tobias Gensch, Dongbing Zhao, Linda Stegemann, Cristian A. Strassert, Frank Glorius

Research output: Contribution to journalArticlepeer-review

121 Scopus citations

Abstract

The first C-H bond activation with pyridotriazoles as coupling partners is presented using a RhIII catalyst. The pyridotriazoles can be used as new carbene precursors in C-H activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.

Original languageEnglish
Pages (from-to)10975-10979
Number of pages5
JournalAngewandte Chemie - International Edition
Volume54
Issue number37
DOIs
StatePublished - 1 Sep 2015

Keywords

  • C-H activation
  • carbene
  • fluorophore
  • rhodium
  • triazole

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