RhIII-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

Ju Hyun Kim; Tobias Gensch; Dongbing Zhao; Linda Stegemann; Cristian A. Strassert; Frank Glorius

doi:10.1002/anie.201504757

Rh^III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

Ju Hyun Kim
, Tobias Gensch
, Dongbing Zhao
, Linda Stegemann
, Cristian A. Strassert
, Frank Glorius

Department of Chemistry

University of Münster

Research output: Contribution to journal › Article › peer-review

128 Scopus citations

Abstract

The first C-H bond activation with pyridotriazoles as coupling partners is presented using a Rh^III catalyst. The pyridotriazoles can be used as new carbene precursors in C-H activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.

Original language	English
Pages (from-to)	10975-10979
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	37
DOIs	https://doi.org/10.1002/anie.201504757
State	Published - 1 Sep 2015

Keywords

C-H activation
carbene
fluorophore
rhodium
triazole

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10.1002/anie.201504757

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title = "RhIII-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection",

abstract = "The first C-H bond activation with pyridotriazoles as coupling partners is presented using a RhIII catalyst. The pyridotriazoles can be used as new carbene precursors in C-H activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.",

keywords = "C-H activation, carbene, fluorophore, rhodium, triazole",

author = "Kim, \{Ju Hyun\} and Tobias Gensch and Dongbing Zhao and Linda Stegemann and Strassert, \{Cristian A.\} and Frank Glorius",

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T1 - RhIII-Catalyzed C-H Activation with Pyridotriazoles

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AU - Kim, Ju Hyun

AU - Gensch, Tobias

AU - Zhao, Dongbing

AU - Stegemann, Linda

AU - Strassert, Cristian A.

AU - Glorius, Frank

PY - 2015/9/1

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AB - The first C-H bond activation with pyridotriazoles as coupling partners is presented using a RhIII catalyst. The pyridotriazoles can be used as new carbene precursors in C-H activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.

KW - C-H activation

KW - carbene

KW - fluorophore

KW - rhodium

KW - triazole

UR - https://www.scopus.com/pages/publications/84940897270

U2 - 10.1002/anie.201504757

DO - 10.1002/anie.201504757

M3 - Article

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AN - SCOPUS:84940897270

SN - 1433-7851

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SP - 10975

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Rh^III-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

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Keywords

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