Roles of interfacial TiOx N1-x layer and TiN electrode on bipolar resistive switching in TiN/ TiO2 /TiN frameworks

June Sik Kwak, Young Ho Do, Yoon Cheol Bae, Hyun Sik Im, Jong Hee Yoo, Min Gyu Sung, Yun Taek Hwang, Jin Pyo Hong

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51 Scopus citations

Abstract

Reversible counter-clockwise and clockwise resistive switching in a TiN/ TiO2 /TiN structure was studied by different polarities of bias voltage. The nature of the bipolar switching phenomenon is related to the creation and annihilation of filament paths caused by redox reactions at locally confined interfaces between the TiO2 layer and TiN electrode. The analysis of electron energy loss spectroscopy (EELS) confirmed the formation of interfacial TiOx N1-x layer between the TiO2 and TiN bottom electrode. The TiOx N1-x layer reduces current levels of ON and OFF states by partially blocking oxygen ion drift to the TiN bottom electrode.

Original languageEnglish
Article number223502
JournalApplied Physics Letters
Volume96
Issue number22
DOIs
StatePublished - 31 May 2010

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