Sequential chemical bath deposition of Cu2-xSe/CdS film by suppressing ion-exchange reaction

Gangri Cai, Iseul Lim, Deok Yeon Lee, Nabeen K. Shrestha, Joong Kee Lee, Yoon Chae Nah, Wonjoo Lee, Sung Hwan Han

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Chemical bath deposition is an attractive technique to form single- and multilayered metal oxide/chalcogenide films on electrode surfaces. However, the occurrence of desorption and/or ion-exchange reaction during subsequent chemical bath deposition has so far limited preparation of multilayered metal oxide/chalcogenide films. In this paper, we report a method to prevent desorption and ion-exchange reaction of metal oxide/chalcogenide on electrode surfaces using a polyelectrolyte multilayer during sequential chemical bath deposition. By controlling the ion permeability of the polyelectrolyte multilayer, Cu2-xSe film was successfully deposited on the CdS film. The Cu2-xSe/CdS film is confirmed by UV-vis absorption spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis, and X-ray powder diffractometer. Furthermore, the Cu2-xSe/CdS films were investigated as photoinduced charge transfer devices which showed photocurrents of 0.22 mA/cm2 under illumination (I = 100 mW/cm2).

Original languageEnglish
Pages (from-to)7176-7180
Number of pages5
JournalJournal of Physical Chemistry B
Volume116
Issue number24
DOIs
StatePublished - 21 Jun 2012

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