Simple metal-free dyes derived from fluorene for visually transparent solar cells: A comparative study of different anchoring groups and electrolytes

Mutia Anissa Marsya, Dini Hayati, Sooyoung Han, Dang Xuan Long, Jun Yeong Ryu, Jae Joon Lee, Kyungah Choi, Jongin Hong

Research output: Contribution to journalArticlepeer-review

Abstract

We present a straightforward synthesis of UV-harvesting dyes featuring a fluorene donor with different anchoring groups, such as cyano acetic acid, amino benzoic acid, and 2-methyl-quinoline-6-carboxylic acid (designated as FCA, FAB, and FQA, respectively). We comprehensively investigate the spectroscopic, electrochemical and colorific properties of these dyes and evaluate their suitability as photosenstizers in visually transparent and colorless dye-sensitized solar cells (DSSCs). FCA and FQA possessing planar geometries exhibit remarkably efficient collection of UV photons, leading to excellent power-conversion-efficiencies (PCEs) under UVA radiation. Furthermore, we explore the incorporation of the binary redox couple, (I,Br)/(I3,I2Br), to enhance the ability to transmit visible light, positively impacting their color rendering properties, while preserving their light harvesting capacities.

Original languageEnglish
Article number111691
JournalDyes and Pigments
Volume220
DOIs
StatePublished - Dec 2023

Keywords

  • Color rendering index
  • Dye-sensitized solar cells
  • Photosensitizer
  • Transmittance
  • Ultraviolet

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