Solvent assisted photochemical formation of a new keto[3,3]paracyclophane

Ho Suk Shin; Da Yoon Moon; Sejin An; Bong Ser Park

doi:10.1039/d2ob00660j

Solvent assisted photochemical formation of a new keto[3,3]paracyclophane

Ho Suk Shin
, Da Yoon Moon
, Sejin An
, Bong Ser Park

Department of Chemistry

Dongguk University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.

Original language	English
Pages (from-to)	4303-4308
Number of pages	6
Journal	Organic and Biomolecular Chemistry
Volume	20
Issue number	21
DOIs	https://doi.org/10.1039/d2ob00660j
State	Published - 6 May 2022

Access to Document

10.1039/d2ob00660j

Cite this

@article{081f2ae23d6d4b8889eacd28dc4757b4,

title = "Solvent assisted photochemical formation of a new keto[3,3]paracyclophane",

abstract = "Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.",

author = "Shin, \{Ho Suk\} and Moon, \{Da Yoon\} and Sejin An and Park, \{Bong Ser\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = may,

day = "6",

doi = "10.1039/d2ob00660j",

language = "English",

volume = "20",

pages = "4303--4308",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Solvent assisted photochemical formation of a new keto[3,3]paracyclophane

AU - Shin, Ho Suk

AU - Moon, Da Yoon

AU - An, Sejin

AU - Park, Bong Ser

PY - 2022/5/6

Y1 - 2022/5/6

N2 - Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.

AB - Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.

UR - https://www.scopus.com/pages/publications/85132840264

U2 - 10.1039/d2ob00660j

DO - 10.1039/d2ob00660j

M3 - Article

AN - SCOPUS:85132840264

SN - 1477-0520

VL - 20

SP - 4303

EP - 4308

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 21

ER -

Solvent assisted photochemical formation of a new keto[3,3]paracyclophane

Abstract

Access to Document

Other files and links

Fingerprint

Cite this