Substituent effect on diastereoselectivity in photochemistry of valerophenone

Ser Park Bong, Sungsu Cho, Sang Hyuk Chong

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Valerophenone shows a dramatic shift of photoreactivity by a cyclopropyl group at alpha position to the carbonyl group. By the minor change of structure, the diastereoselectivity of the Yang photocyclization is reversed and the ratio of cyclization to elimination products increases significantly.

Original languageEnglish
Pages (from-to)1156-1158
Number of pages3
JournalBulletin of the Korean Chemical Society
Volume28
Issue number7
DOIs
StatePublished - 20 Jul 2007

Keywords

  • Diastereoselectivity
  • Photochemistry
  • Substituent effect
  • Valerophenone

Fingerprint

Dive into the research topics of 'Substituent effect on diastereoselectivity in photochemistry of valerophenone'. Together they form a unique fingerprint.

Cite this