Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone

Atanu Jana; Saugata Konar; Sangita Ray; Shie Ming Peng; G. H. Lee; Ray J. Butcher; Tian Huey Lu; Anil Kumar Barik; Sachindranath Pal; Susanta Kumar Kar

Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone

Atanu Jana, Saugata Konar, Sangita Ray, Shie Ming Peng, G. H. Lee, Ray J. Butcher, Tian Huey Lu, Anil Kumar Barik, Sachindranath Pal, Susanta Kumar Kar

Division of System Semiconductor

Research output: Contribution to journal › Article › peer-review

Abstract

Two cobalt(III) complexes [Co(L¹)2]ClO₄ (1) [HL ¹= N-ethyl-2-((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and [Co(L²)₂]ClO ₄.CH₃OH.H₂O (2) [HL²=N,N-dimethyl-2- ((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and one nickel(II) complex [Ni(HL³)2](ClO₄)₂.2H ₂O (3) [HL³=(2E)-N-ethyl-2-((6-methyl-2-(methylsulfanyl) pyrimidin-4-yl)methylidene)-hydrazinecarbothioamide] have been prepared and characterized by spectroscopic studies and X-ray diffraction measurements. Structural study reveals that the coordination environment around each metal center is distorted octahedral. The two tridentate (NNS) uninegative pyrazole derived ligands in the cobalt(III) complexes (1 and 2) and the two similar neutral pyrimidine derived ligands in the nickel(II) complex (3) are coordinated to the central metal ions in the meridional fashion. The pyrazole N and thiolato S in (1) and (2) and pyrimidine N and thione S in (3) are cis to each other while azomethine N atoms are trans coordinated.

Original language	English
Pages (from-to)	1334-1342
Number of pages	9
Journal	Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume	50
Issue number	9-10
State	Published - Sep 2011

Keywords

Cobalt
Coordination chemistry
Nickel
Pyrazoles
Pyrimidines
Thiosemicarbazones
X-ray structure

Fingerprint

Dive into the research topics of 'Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone'. Together they form a unique fingerprint.

Cite this

Jana, A., Konar, S., Ray, S., Peng, S. M., Lee, G. H., Butcher, R. J., Lu, T. H., Barik, A. K., Pal, S., & Kar, S. K. (2011). Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 50(9-10), 1334-1342.

Jana, Atanu ; Konar, Saugata ; Ray, Sangita et al. / Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone. In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry. 2011 ; Vol. 50, No. 9-10. pp. 1334-1342.

@article{b5222e2fd30c452cabfb7355e23dde80,

title = "Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone",

abstract = "Two cobalt(III) complexes [Co(L1)2]ClO4 (1) [HL 1= N-ethyl-2-((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and [Co(L2)2]ClO 4.CH3OH.H2O (2) [HL2=N,N-dimethyl-2- ((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and one nickel(II) complex [Ni(HL3)2](ClO4)2.2H 2O (3) [HL3=(2E)-N-ethyl-2-((6-methyl-2-(methylsulfanyl) pyrimidin-4-yl)methylidene)-hydrazinecarbothioamide] have been prepared and characterized by spectroscopic studies and X-ray diffraction measurements. Structural study reveals that the coordination environment around each metal center is distorted octahedral. The two tridentate (NNS) uninegative pyrazole derived ligands in the cobalt(III) complexes (1 and 2) and the two similar neutral pyrimidine derived ligands in the nickel(II) complex (3) are coordinated to the central metal ions in the meridional fashion. The pyrazole N and thiolato S in (1) and (2) and pyrimidine N and thione S in (3) are cis to each other while azomethine N atoms are trans coordinated.",

keywords = "Cobalt, Coordination chemistry, Nickel, Pyrazoles, Pyrimidines, Thiosemicarbazones, X-ray structure",

author = "Atanu Jana and Saugata Konar and Sangita Ray and Peng, {Shie Ming} and Lee, {G. H.} and Butcher, {Ray J.} and Lu, {Tian Huey} and Barik, {Anil Kumar} and Sachindranath Pal and Kar, {Susanta Kumar}",

year = "2011",

month = sep,

language = "English",

volume = "50",

pages = "1334--1342",

journal = "Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry",

issn = "0376-4710",

publisher = "Scientific Publishers of India",

number = "9-10",

}

Jana, A, Konar, S, Ray, S, Peng, SM, Lee, GH, Butcher, RJ, Lu, TH, Barik, AK, Pal, S & Kar, SK 2011, 'Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone', Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, vol. 50, no. 9-10, pp. 1334-1342.

Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone. / Jana, Atanu; Konar, Saugata; Ray, Sangita et al.
In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, Vol. 50, No. 9-10, 09.2011, p. 1334-1342.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone

AU - Jana, Atanu

AU - Konar, Saugata

AU - Ray, Sangita

AU - Peng, Shie Ming

AU - Lee, G. H.

AU - Butcher, Ray J.

AU - Lu, Tian Huey

AU - Barik, Anil Kumar

AU - Pal, Sachindranath

AU - Kar, Susanta Kumar

PY - 2011/9

Y1 - 2011/9

N2 - Two cobalt(III) complexes [Co(L1)2]ClO4 (1) [HL 1= N-ethyl-2-((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and [Co(L2)2]ClO 4.CH3OH.H2O (2) [HL2=N,N-dimethyl-2- ((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and one nickel(II) complex [Ni(HL3)2](ClO4)2.2H 2O (3) [HL3=(2E)-N-ethyl-2-((6-methyl-2-(methylsulfanyl) pyrimidin-4-yl)methylidene)-hydrazinecarbothioamide] have been prepared and characterized by spectroscopic studies and X-ray diffraction measurements. Structural study reveals that the coordination environment around each metal center is distorted octahedral. The two tridentate (NNS) uninegative pyrazole derived ligands in the cobalt(III) complexes (1 and 2) and the two similar neutral pyrimidine derived ligands in the nickel(II) complex (3) are coordinated to the central metal ions in the meridional fashion. The pyrazole N and thiolato S in (1) and (2) and pyrimidine N and thione S in (3) are cis to each other while azomethine N atoms are trans coordinated.

AB - Two cobalt(III) complexes [Co(L1)2]ClO4 (1) [HL 1= N-ethyl-2-((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and [Co(L2)2]ClO 4.CH3OH.H2O (2) [HL2=N,N-dimethyl-2- ((5-methyl-1H-pyrazol-3-yl)methylidene) hydrazinecarbothioamide] and one nickel(II) complex [Ni(HL3)2](ClO4)2.2H 2O (3) [HL3=(2E)-N-ethyl-2-((6-methyl-2-(methylsulfanyl) pyrimidin-4-yl)methylidene)-hydrazinecarbothioamide] have been prepared and characterized by spectroscopic studies and X-ray diffraction measurements. Structural study reveals that the coordination environment around each metal center is distorted octahedral. The two tridentate (NNS) uninegative pyrazole derived ligands in the cobalt(III) complexes (1 and 2) and the two similar neutral pyrimidine derived ligands in the nickel(II) complex (3) are coordinated to the central metal ions in the meridional fashion. The pyrazole N and thiolato S in (1) and (2) and pyrimidine N and thione S in (3) are cis to each other while azomethine N atoms are trans coordinated.

KW - Cobalt

KW - Coordination chemistry

KW - Nickel

KW - Pyrazoles

KW - Pyrimidines

KW - Thiosemicarbazones

KW - X-ray structure

UR - http://www.scopus.com/inward/record.url?scp=80054096799&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:80054096799

SN - 0376-4710

VL - 50

SP - 1334

EP - 1342

JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

IS - 9-10

ER -

Jana A, Konar S, Ray S, Peng SM, Lee GH, Butcher RJ et al. Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry. 2011 Sep;50(9-10):1334-1342.

Synthesis and structural studies of cobalt(III) complexes of 5-methyl-3-formylpyrazole-N(4)-ethyl/dimethyl thiosemicarbazone and nickel(II) complex of 2-S-methyl-6-methyl-4-formylpyrimidine-N(4)-ethyl thiosemicarbazone

Abstract

Keywords

Other files and links

Fingerprint

Cite this