Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries

Peng Li; Jingyan Liu; Yuwei Wang; Yang Liu; Xiuna Wang; Kyung Wan Nam; Yong Mook Kang; Mingbo Wu; Jieshan Qiu

doi:10.1016/j.cej.2015.10.102

Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries

Peng Li, Jingyan Liu, Yuwei Wang, Yang Liu, Xiuna Wang, Kyung Wan Nam, Yong Mook Kang, Mingbo Wu, Jieshan Qiu

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

Petroleum asphalt based ultrathin hollow carbon shell (PACS) was prepared via a facile template-assisted method. As the anode material of lithium-ion batteries, PACS exhibits high reversible capacity, excellent cycling stability, and superior rate performance. A high reversible capacity of 334mAhg^-1 and 90% kept of the theoretical capacity can still be maintained in PACS at a current density of 1Ag^-1 even after 1000 cycles, which is ascribed to the unique hollow structure, ultrathin porous shells (4.7nm), the doped nitrogen atoms, and high level of disorder degree. Meanwhile, the present study paves a milestone for the high-valued utilization of petroleum asphalt and other kinds of heavy oil.

Original language	English
Pages (from-to)	632-639
Number of pages	8
Journal	Chemical Engineering Journal
Volume	286
DOIs	https://doi.org/10.1016/j.cej.2015.10.102
State	Published - 15 Feb 2016

Keywords

Carbon materials
Carbon shell
Energy storage and conversion
Lithium-ion battery
Petroleum asphalt

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.cej.2015.10.102

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title = "Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries",

abstract = "Petroleum asphalt based ultrathin hollow carbon shell (PACS) was prepared via a facile template-assisted method. As the anode material of lithium-ion batteries, PACS exhibits high reversible capacity, excellent cycling stability, and superior rate performance. A high reversible capacity of 334mAhg-1 and 90% kept of the theoretical capacity can still be maintained in PACS at a current density of 1Ag-1 even after 1000 cycles, which is ascribed to the unique hollow structure, ultrathin porous shells (4.7nm), the doped nitrogen atoms, and high level of disorder degree. Meanwhile, the present study paves a milestone for the high-valued utilization of petroleum asphalt and other kinds of heavy oil.",

keywords = "Carbon materials, Carbon shell, Energy storage and conversion, Lithium-ion battery, Petroleum asphalt",

author = "Peng Li and Jingyan Liu and Yuwei Wang and Yang Liu and Xiuna Wang and Nam, {Kyung Wan} and Kang, {Yong Mook} and Mingbo Wu and Jieshan Qiu",

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journal = "Chemical Engineering Journal",

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T1 - Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries

AU - Li, Peng

AU - Liu, Jingyan

AU - Wang, Yuwei

AU - Liu, Yang

AU - Wang, Xiuna

AU - Nam, Kyung Wan

AU - Kang, Yong Mook

AU - Wu, Mingbo

AU - Qiu, Jieshan

PY - 2016/2/15

Y1 - 2016/2/15

N2 - Petroleum asphalt based ultrathin hollow carbon shell (PACS) was prepared via a facile template-assisted method. As the anode material of lithium-ion batteries, PACS exhibits high reversible capacity, excellent cycling stability, and superior rate performance. A high reversible capacity of 334mAhg-1 and 90% kept of the theoretical capacity can still be maintained in PACS at a current density of 1Ag-1 even after 1000 cycles, which is ascribed to the unique hollow structure, ultrathin porous shells (4.7nm), the doped nitrogen atoms, and high level of disorder degree. Meanwhile, the present study paves a milestone for the high-valued utilization of petroleum asphalt and other kinds of heavy oil.

AB - Petroleum asphalt based ultrathin hollow carbon shell (PACS) was prepared via a facile template-assisted method. As the anode material of lithium-ion batteries, PACS exhibits high reversible capacity, excellent cycling stability, and superior rate performance. A high reversible capacity of 334mAhg-1 and 90% kept of the theoretical capacity can still be maintained in PACS at a current density of 1Ag-1 even after 1000 cycles, which is ascribed to the unique hollow structure, ultrathin porous shells (4.7nm), the doped nitrogen atoms, and high level of disorder degree. Meanwhile, the present study paves a milestone for the high-valued utilization of petroleum asphalt and other kinds of heavy oil.

KW - Carbon materials

KW - Carbon shell

KW - Energy storage and conversion

KW - Lithium-ion battery

KW - Petroleum asphalt

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U2 - 10.1016/j.cej.2015.10.102

DO - 10.1016/j.cej.2015.10.102

M3 - Article

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SN - 1385-8947

VL - 286

SP - 632

EP - 639

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

ER -

Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries

Abstract

Keywords

UN SDGs

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