TY - JOUR
T1 - Utilizing Waste Thermocol Sheets and Rusted Iron Wires to Fabricate Carbon–Fe3O4 Nanocomposite-Based Supercapacitors
T2 - Turning Wastes into Value-Added Materials
AU - Vadiyar, Madagonda M.
AU - Liu, Xudong
AU - Ye, Zhibin
N1 - Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2018/7/20
Y1 - 2018/7/20
N2 - The synthesis of porous activated carbon (specific surface area=1883 m2 g−1), Fe3O4 nanoparticles, and carbon–Fe3O4 (C−Fe3O4) nanocomposites from local waste thermocol sheets and rusted iron wires is demonstrated herein. The resulting carbon, Fe3O4 nanoparticles, and C−Fe3O4 composites are used as electrode materials for supercapacitor applications. In particular, C−Fe3O4 composite electrodes exhibit a high specific capacitance of 1375 F g−1 at 1 A g−1 and longer cyclic stability with 98 % capacitance retention over 10 000 cycles. Subsequently, an asymmetric supercapacitor, namely, C−Fe3O4∥Ni(OH)2/carbon nanotube device, exhibits a high energy density of 91.1 Wh kg−1 and a remarkable cyclic stability, with 98 % capacitance retention over 10 000 cycles. Thus, this work has important implications not only for the fabrication of low-cost electrodes for high-performance supercapacitors, but also for the recycling of waste thermocol sheets and rusted iron wires for value-added reuse.
AB - The synthesis of porous activated carbon (specific surface area=1883 m2 g−1), Fe3O4 nanoparticles, and carbon–Fe3O4 (C−Fe3O4) nanocomposites from local waste thermocol sheets and rusted iron wires is demonstrated herein. The resulting carbon, Fe3O4 nanoparticles, and C−Fe3O4 composites are used as electrode materials for supercapacitor applications. In particular, C−Fe3O4 composite electrodes exhibit a high specific capacitance of 1375 F g−1 at 1 A g−1 and longer cyclic stability with 98 % capacitance retention over 10 000 cycles. Subsequently, an asymmetric supercapacitor, namely, C−Fe3O4∥Ni(OH)2/carbon nanotube device, exhibits a high energy density of 91.1 Wh kg−1 and a remarkable cyclic stability, with 98 % capacitance retention over 10 000 cycles. Thus, this work has important implications not only for the fabrication of low-cost electrodes for high-performance supercapacitors, but also for the recycling of waste thermocol sheets and rusted iron wires for value-added reuse.
KW - carbon
KW - electrochemistry
KW - iron
KW - nanoparticles
KW - supercapacitors
UR - http://www.scopus.com/inward/record.url?scp=85050373383&partnerID=8YFLogxK
U2 - 10.1002/cssc.201800852
DO - 10.1002/cssc.201800852
M3 - Article
C2 - 29761664
AN - SCOPUS:85050373383
SN - 1864-5631
VL - 11
SP - 2410
EP - 2420
JO - ChemSusChem
JF - ChemSusChem
IS - 14
ER -