Visible light-driven photocatalytic rapid degradation of organic contaminants engaging manganese dioxide-incorporated iron oxide three dimensional nanoflowers

Water pollution via hazardous organic pollutants poses a high threat to the environment and globally imperils aquatic life and human health. Therefore, the elimination of toxic organic waste from water sources is vital to ensure a healthy green environment. In the current work, we synthesized α-MnO₂-Fe₃O₄ 3D-flower like structure using a two-step hydrothermal method and explored the combination in a visible-light-assisted photocatalytic degrdation of dyes. The attained high specific surface area of 82 m²/g with mesoporous nature of α-MnO₂ and Fe₃O₄ together can generate more active sites after exposure to visible light, leading to remarkable photodegradation performance. Significantly, twofold higher dye (methylene blue, MB (94.8%/120 min; crystal violet, CV (93.7%/120 min)) and drug (LVO 91%/90 min) photodegradations were observed with α-MnO₂-Fe₃O₄ as catalyst than pure α-MnO₂ and Fe₃O₄ at pH 6, respectively. This is attributed to the higher surface area and synergistic effect between Mn and Fe. More than 85% stability was observed with optimized catalysts employing MB and CV dyes, demonstrating the excellent reusability of the α-MnO₂-Fe₃O₄. The underlying mechanism indicates that the formation of reactive oxygen species predominantly plays a role in the photodegradation of dyes under visible light. Consequently, these new insights will shed light on the practical applications of the α-MnO₂-Fe₃O₄ 3D-flower-like spherical structure for eco-friendly remediation via wastewater treatment.