Z-Scheme Heterojunction of 3-Dimensional Hierarchical Bi₃O₄Cl/Bi₅O₇I for a Significant Enhancement in the Photocatalytic Degradation of Organic Pollutants (RhB and BPA)

In this study, we report the synthesis of a 3-dimensional (3D) hierarchical Bi₃O₄Cl/Bi₅O₇I (BOC/BOI) heterostructure for the photocatalytic degradation of Rhodamine-B (RhB) dye and color-less Bisphenol-A (BPA) pollutant under visible light. The heterostructure was prepared using in situ solvothermal and calcination methods. BOC/BOI exhibits a 3D hierarchical structure constructed with thin nano-platelets. The photocatalytic performance of the BOC/BOI photocatalyst demonstrated that the degradation efficiencies of RhB and BPA were 97% and 92% after light illumination within 90 and 30 min, respectively. In comparison, bare BOC and BOI efficiencies were only 20% and 10% for RhB dye, respectively, and 2.3% and 37% for BPA aqueous pollutants, respectively. Moreover, radical trapping measurements indicated that •O₂⁻ and •OH radicals played prominent roles in RhB and BPA degradation into mineralization. Analysis of band structures and photochemical redox reactions of BOC/BOI revealed a Z-scheme charge transfer between BOC and BOI by an internal electric field formed at the interface. Therefore, the highly improved photocatalytic performance of the BOC/BOI heterostructure is attributed to the synergetic effects of large surface area, high visible-light absorption, and the enhanced separation and transport of photo-excited electron–hole pairs induced by the hierarchical and Z-scheme heterojunction of the BOC/BOI.