Zwitterion-assisted transition metal dichalcogenide nanosheets for scalable and biocompatible inkjet printing

Inkjet printing of two-dimensional (2D) transition metal dichalcogenide (TMD) nanosheets fabricated by liquid-phase exfoliation (LPE) allows simple, mass-producible, and low-cost photo-electronic devices. Many LPE processes involve toxic and environmentally hazardous solvents; however, dispersants have restricted the extent of applications of 2D-TMD inks. Herein, various 2D-TMD nanosheets, including MoS₂, MoSe₂, WS₂, and WSe₂, in addition to few-layered graphene, are inkjet-printed using a LPE process based on zwitterionic dispersants in water. Zwitterions with cationic and anionic species are water-soluble, while alkyl chain moieties associated with two ionic species adhere universally on the surface of TMD nanosheets, resulting in high throughput liquid exfoliation of the nanosheets. The zwitterion-assisted TMD nanosheets in water are successfully employed as an ink without the need for additives to adjust the viscosity and surface tension of the ink for use in an office inkjet printer; this gives rise to A4 scale, large-area inkjet-printed images on diverse substrates, such as metals, oxides, and polymer substrates patchable onto human skin. Combination with conductive graphene nanosheet inks allowed the development of mechanically flexible, biocompatible-printed arrays of photodetectors with pixelated MoSe₂ channels on a paper exhibiting a photocurrent ON/OFF ratio of approximately 10^3.8 and photocurrent switching of 500 ms. [Figure not available: see fulltext.].